Tuesday, February 27, 2024

Today's KNOWLEDGE Share:PVC in Healthcare

Today's KNOWLEDGE Share

PVC Safe and Effective in Medical Devices and Packaging, Study Claims

A new report by the European Chemicals Agency confirms the safe production of PVC in Europe and recognizes its importance in medical device and packaging applications.


A new report claiming that the use of PVC in medical devices and packaging does not pose a significant healthcare risk to those who manufacture the products or to the global environment is garnering industry recognition.


Conducted by the European Chemicals Agency (ECHA), the report confirms the safe production of PVC in Europe and concludes there is no data supporting better alternatives to PVC from a life-cycle perspective. The report also acknowledges the significance of utilizing PVC in medical devices and packaging.


The findings are being touted by the European Council of Vinyl Manufacturers’ (ECVM) PVCMed Alliance, a platform that seeks to raise awareness about the use of PVC in healthcare. In a statement released this week, the PVCMed Alliance shared support of the investigative analysis, which covers the use of PVC and PVC additives as well as a comprehensive analysis of PVC's role in medical devices and packaging, among other topics. The report also confirms that the production of PVC in Europe adheres to the highest safety standards and highlights significant advances in the European PVC industry.

"It is heartening to see ECHA's findings align with our understanding of how PVC is produced today," said Ole Grøndahl Hansen, project leader at PVCMed Alliance. "We are also happy about the nuanced approach to PVC’s role in healthcare from a high-level European authority. We hope the report will contribute to more evidence-based procurement decisions among European hospitals and [boost] consideration of PVC’s potential carbon savings through recycling."


Other points of emphasis within the ECHA report include:

No single alternative material has been identified as a replacement for PVC in all its medical applications, which underscores the polymer’s irreplaceable role in healthcare, according to the PVCMed Alliance. 


There is no life-cycle assessment (LCA) data to substantiate the claim that alternatives are environmentally preferable to PVC.

Advances made in developing new plasticizers address health concerns related to low-molecular-weight phthalates, such as di(2- ethylhexyl) phthalate (DEHP).

PVC's versatility and cost/performance ratio in medical packaging, particularly in blister packs, are unrivalled.

The formation of dioxins is not directly linked to the amount of chlorine present in waste. Instead, dioxin production is mainly influenced by the management of the incineration process. Current European waste incineration capacity is adequate to safely process waste containing up to 2% PVC.

Significant advances in the European PVC industry have been made through the VinylPlus Commitment to sustainable development.


source:www.plasticstoday.com


Monday, February 26, 2024

Today's KNOWLEDGE Share:Molding at Constant pressure

Today's KNOWLEDGE Share

Historically, early injection molding machines would essentially be pressure controlled.Many good parts have been made under such process control. So, it is not all bad !


However, note that when molding an end-gated fairly long part, a constant pressure fill translates into an ever decreasing melt front velocity, as the pressure drop builds up.

This in turns corresponds to a decreasing average temperature of the melt front along the flow.


Such a decreasing T will create an increasingly strong degree of molecular orientation when moving away from the gate. The part, especially when using semi-crystalline grades, will have a strong gradient of mechanical properties along the flow which could be as serious as showing good ductility near the gate and severe brittleness far from the gate.


source:Vito leo

Flax fibre revolution: sustainable composites enter automotive production with the Volvo EX30

Legislation, competition and electrification are driving significant inno­vation in the transport sector. The automotive industry’s emphasis on zero-emission vehicles aligns with broader efforts to reduce carbon emissions, with a growing focus on sustainable materials beyond batteries and electric motors.



“This is a transformative time for many industries, with com­panies assessing and evolving in line with government demands and consumer expectations, said Per Mårtensson. Responses can range from mitigating the envi­ronmental toll of raw materials and production to improved waste management, as well as developing new technologies that deliver efficiency gains. In the au­tomotive industry, this translates into an increased emphasis on circular, recycled and sustainable materials to support the goal of zero emission vehicles.”


Weight reduction on the scope

One of the current methods used to enhance vehicle effi­ciency is lightweighting, regard­less of the propulsion system. Consequently, manufacturers are actively seeking solutions to diminish the overall mass of ve­hicles while upholding environ­mental considerations. This en­deavour is particularly notable in the sector of electric vehicles (EVs), where battery weight impacts both efficiency and driving range. “The rapid rise of EVs has been a huge shift for the automotive industry, bringing forth new challenges, continued Per Mårtensson.


The weight reduction trend was already present, but now it has intensified as more OEMs recog­nise the significance of sustainable lightweighting, dematerialisation, as well as the need for viable and circular end-of-life options for the materials used.”

The viable, circular options Per Mårtensson refers to just happens to include ampliTex™, Bcomp’s flax fibre-based com­posite technology. It has been featured in a wide variety of ap­plications from tennis rackets and skis to motorsport wings, satellite panels, where its use and that of Bcomp power­Ribs™ have been a resounding success. Now, the company has achieved the long-term goal of integrating its technology into a production vehicle, the new Volvo EX30 small fully electric SUV. With the lowest carbon footprint of any model in Volvo Cars’ history (the lowest carbon footprint of any Volvo car to date statement relates to available products over 200,000 km of driving), the EX30 is launching with the op­tion for innovative natural fibre composites in its dashboard and door trim.


“Bcomp’s work with Volvo Cars to integrate the Bcomp ampli­Tex™ into a global production ve­hicle has been ambitious, reward­ing, and significant”, according to Per Mårtensson. Bcomp tech­nologies have already been used in some of the most extreme scenarios imaginable, but one of the company’s main goals was to efficiently scale and achieve meaningful impact within the transport sector. The inclusion of ampliTex™ panels in a large-scale automotive application is a very exciting advance that highlights the opportunities for forward-thinking vehicle manu­facturers.

A fruitful collaboration

The collaboration between Volvo Cars and Bcomp began in 2018, during the Volvo Ocean Race recycled plastics demonstrator vehicle project, which focused on using recycled and circular materials. This prototype vehicle incorporated powerRibs™ into several semi-structural interior elements, garnering attention from Volvo’s engineering team. In turn, this lead to inclusion of Bcomp technologies in the Volvo Concept Recharge a few years later.

The EX30 is available with four interior specifications, known as ‘rooms’ which provide a distinct ambiance. Two of these rooms include high-quality parts made from ampliTex™, a technical fab­ric made of a flax textile weave. Derived from renewable Eu­ropean-grown flax, ampliTex™ harnesses the natural aesthetic and mechanical characteristics of flax fibres. This fabric enables the production of lightweight high-performance composites with a distinct aesthetic and excellent vibration damping – perfect for interior.

Source:bcomp/jeccomposites

Sunday, February 25, 2024

Today's KNOWLEDGE Share :The main properties of composite materials

Today's KNOWLEDGE Share

The main properties of composite materials!


As you may know, the characteristics/properties of composite materials resulting from the combination of reinforcement and matrix depend on: the proportions of reinforcements and matrix, the form of the reinforcement, and the fabrication process. 



But what are the most remarkable properties of these materials? 


- Composite materials generally possess very high specific mechanical properties.

- Composite materials do not yield: their elastic limits correspond to the rupture limit.

- Composite materials have high strength under fatigue loads.

- Composite materials age under the action of moisture and heat.

- Composite materials do not corrode, except in the case of contact aluminum with carbon fibers in which galvanic phenomenon creates rapid corrosion.

- Composite materials are not sensitive to the common chemicals used in engines: grease, oils, hydraulic liquids, paints and solvents, petroleum. However, cleaners for paint attack the epoxy resins.

- Composite materials have medium- to low-level impact resistance (inferior to that of metallic materials).

- Composite materials have excellent fire resistance as compared with the light alloys with identical thicknesses. However, the smoke emitted from the combustion of certain matrices can be toxic.


Bibliographical Reference:

Composite Materials Design and Applications - Page 16


source:managingcomposites


Friday, February 23, 2024

EPA Announces New Measures to Address PFAS Pollution and Other Concerned Chemical

The U.S. Environmental Protection Agency announced the latest efforts to protect communities and the environment from the health risks posed by certain PFAS.

PFAS are widely used, long-lasting chemicals that break down slowly over time. They have been used in many different consumer, commercial, and industrial products. Scientific studies show that some PFAS exposure is linked to harmful health effects.


Will Deliver the Agenda to Protect Public Health


EPA is proposing two rules that would add to the agency’s comprehensive approach to tackling PFAS pollution across the country. These proposals will also help deliver on President Biden’s agenda to better protect public health and advance environmental justice.


“From day one, President Biden promised to address harmful forever chemicals and other emerging contaminants to better protect communities from exposure, and today’s actions are just the latest from EPA as we continue to deliver on the president’s commitment,” said EPA administrator Michael S. Regan. “Thanks to strong partnerships with our co-regulators in the states, we will strengthen our ability to clean up contamination from PFAS, hold polluters accountable and advance public health protections.”


“States like New Mexico are on the front lines of protecting communities from forever chemicals, and stronger federal regulations are essential in addressing such contamination,” said New Mexico Gov. Michelle Lujan Grisham. “EPA’s proposed rules are a direct result of New Mexico’s leadership in holding polluters accountable by treating PFAS like the toxic waste they are.”


Proposing to Modify Definition of Hazardous Waste


EPA is proposing to modify the definition of hazardous waste. The definition applies to cleanups at permitted hazardous waste facilities. This modification would ensure that EPA’s regulations reflect EPA’s and authorized states’ authority. They may require the cleanup of the full range of substances that the Resource Conservation and Recovery Act (RCRA) intended. This includes PFAS, which may present hazards, at permitted facilities. Currently, the regulations do not clearly and accurately reflect the full authority granted to EPA by Congress.


EPA is also proposing to amend its RCRA regulations to add multiple PFAS compounds as hazardous constituents. These PFAS would be added to the list of substances identified for consideration in facility assessments. Where necessary, they would undergo further investigation and cleanup through the corrective action process at hazardous waste treatment, storage, and disposal facilities.

These proposed rules would strengthen protections for communities and drinking water supplies located near the 1,740 permitted hazardous waste facilities across the nation. Corrective action under RCRA requires facilities that treat, store or dispose of hazardous waste to protect health and the environment by investigating and cleaning up hazardous releases into soil, groundwater, surface water, and air. Hazardous waste cleanups are a crucial part of EPA’s focus on environmental justice and help to protect public health in part by addressing disparities in access to a clean and safe environment.

EPA will be publishing these proposals in the Federal Register in the next few weeks. The “Definition of Hazardous Waste Applicable to Corrective Action from Solid Waste Management Units” proposed rule will be open for public comment for 30 days whereas the “Listing of Specific PFAS as Hazardous Constituents” proposed rule will be open for public comment for 60 days. Upon publication, EPA welcomes comments on each proposal.


source:Environmental Protection Agency (EPA)/specialchem

Thursday, February 22, 2024

Today's KNOWLEDGE Share:Mold compression changes cavity by few microns in Injection molding

Today's KNOWLEDGE Share

Based on consulting requests, I realize that a lot of people forget that huge forces are developed during the molding process, as a result of pressure levels exceeding often 1000 bar/100MPa.


That amounts to 1 metric Ton of equivalent force applied to each square cm of tool surface.

That is why clamp tonnage numbers are what they are of course.


But, no matter how good your steel or tool design is, metal will bend significantly when subjected to huge unbalanced forces.


And, even more surprisingly, for balanced forces, the cavity will expand by "compressing" the steel by quite a few microns !

You can run a quick FEA to check that, by applying 1000-2000 bar on a piece of steel.


Of course tubular shaped parts will readily see significant core shift problems as soon as flow is slightly unbalanced, since a differential of a few Tons-force can quickly appear if flow is not perfectly balanced. The problem here is, of course, that the more the core deflects, the more the unbalance grows. So it is a bad case of positive feedback leading to catastrophic results (unexpected weldlines in the thinned side towards which the core has been bent/pushed).


Don't underestimate the importance of these effects in molding.


While coupling Flow Analysis with stress analysis on the steel structure can supposedly model this, it is very challenging to describe the complex tool assembly. And such coupled approaches can be very challenging numerically. So, while core-shifting predictions are now quite standard, full tool deflections are usually neglected in simulations. And the clear tendency of steel compressibility to lead to overpack is never accounted for.


Source:Vito Leo


 #injectionmoulding #polymers

Wednesday, February 21, 2024

Today's KNOWLEDGE Share :The Long-Term Costs of Wind Turbines

Today's KNOWLEDGE Share

The Long-Term Costs of Wind Turbines

In 1859, the town of Titusville in Pennsylvania vaulted into the limelight when Edwin Drake struck oil, thereby marking the inception of America’s oil industry. With an initial depth of 69.5 feet (roughly equivalent to the blade size of a 0.5 MW wind turbine), Drake’s well set the stage for an unprecedented era of economic prosperity.


Companies and workers alike descended upon Pennsylvania’s black-gold frontier, applying rudimentary cable-tool drilling technology to tap shallow reserves. However, as these reserves ran dry, the industry underwent a transformation. With improvements in technology and a better understanding of the geology of oil reservoirs, operators began to go deeper. Rotary drilling techniques, which were more effective than the earlier percussion methods, were introduced and made deeper drilling more feasible. Additionally, improvements in pumping technology enabled oil to be extracted more efficiently from greater depths.


For a while, it seemed like the fountain would flow endlessly. But eventually, Pennsylvania began to run out of extractable oil. Newer and more promising fields were discovered elsewhere, drawing attention and resources away from older sites. But in the absence of regulations, operators simply abandoned their wells without properly capping or decommissioning them. The result is that today Pennsylvania is plagued by more than 8,800 “ghost wells”: abandoned oil wells that continue harming the environment and local communities. Emitting methane and leaking chemicals into groundwater, these wells degrade soil and make land unusable, stalling local development plans and reducing property values.


The development of the turbine industry is eerily reminiscent of Pennsylvania’s forgotten oil rush. In 2021, global wind capacity increased by 94 GW, primarily led by six countries: the United States, China, Germany, India, Spain, and Brazil. This growth in wind power has been accompanied by dramatic cost reductions, making wind energy increasingly competitive. Onshore wind energy costs fell by 68% and offshore by 59%, with 2021 seeing further declines of 15% and 13%, respectively. Over the decade from 2010 to 2021, onshore wind capacity increased four-fold, while offshore capacity grew 11-fold.


Much of this growth has come from making the turbines bigger. Bigger blades on turbines located farther offshore capture wind more efficiently, require fewer turbines for the same output, and offer more consistent energy generation due to steadier offshore winds. These factors also reduce the costs associated with integrating the energy output with national grids. Keen to accelerate this trend, governments around the world offer various financial incentives. France, for example, subsidizes long-term wind-power purchase contracts and supports research and development programs aimed at enhancing the efficiency and cost effectiveness of offshore wind technology.


Unfortunately — and ironically — it also looks like the wind energy business could be repeating the mistakes of the Pennsylvania oil drillers, leaving the public with a legacy that is equally challenging for society. A rush to create power-generation capacity without a comprehensive approach that considers the entire lifecycle of wind farms can result in detrimental consequences for both the environment and the long-term viability of these projects. To ensure the long-term sustainability and viability of wind energy projects, designers and decision-makers should account for various factors throughout the entire lifecycle of a wind farm, including environmental impact and lifecycle costs: capital expenditures, operational expenditures, and end-of-life (EOL) costs.


As larger wind energy projects venture farther offshore to harness more consistent and powerful winds, a proportional escalation in costs across various categories is inevitable. Capital expenditures are not merely a factor of turbine costs; they also encompass the expenses associated with creating robust and durable offshore platforms, marine logistics, and extensive undersea cabling to connect these distant turbines back to the grid onshore. Operational expenditures also see a marked increase due to the complexity and challenge of routine maintenance and repair work in offshore conditions. These tasks become difficult and expensive as the distance from shore increases, often requiring specialized vessels and equipment, not to mention the increased risks that workers will face.


The most significant cost escalation is likely to occur in decommissioning, a complex and expensive endeavor involving the disassembly of turbines, removal of foundations and cables, reverse logistics of moving the blades and towers back to shore, and responsible waste management. Most economic analyses on wind farm design, however, assume that these costs will be negligible or diminish over time. They also underestimate maintenance costs, which are well known to increase over time. Moreover, they do not explore the implications of building larger turbines situated farther offshore on decommissioning and maintenance costs, which are typically set arbitrarily at 50% of the cost of making the turbine.


The industry cannot afford to brush over decommissioning and maintenance issues any longer. Through 2023, turbine operators such as Siemens Energy have incurred rising upkeep costs. (Shares in Siemens plunged 30% after the company announced it would have to spend an additional $1 billion in turbine maintenance.) The first major wave of decommissioning is also imminent, with around 34,000 onshore turbines close to retirement. Awareness of the problem is growing, triggering initiatives like the ZEBRA consortium in Europe, a research program that seeks to design a 100% recyclable wind turbine, while in the U.S., the State of Colorado now mandates the removal of decommissioned wind turbines.


In an effort to understand the economic implications of wind farm maintenance and decommissioning, we collected accessible wind farm data to estimate the construction cost of a single turbine as a function of its blade size and shore distance. We then estimated the total cost by assuming maintenance and end-of-life costs (MEOL) to be a fraction of construction costs and combined these estimates with physical principles of wind generation based on engineering equations involving wind speed distribution, energy generation, and other relevant factors to build a “lifetime value” model, which reveals the relationships between blade size, distance from shore, and turbine lifetime value (the total revenue generated from electricity produced by a turbine minus its total lifecycle cost), as depicted in Figure 1.


As the figure shows, larger turbines are, up to a point, more efficient, absent other factors (chart A). But that efficiency varies with shore distance (chart B), and the optimal blade size is clearly affected by the level of MEOL costs (the apexes of the curves in both parts move leftwards). We can conclude, therefore, that smaller blades can be better suited for farther offshore projects. In other words, suppose that you are considering the construction of a wind farm 35 km shore distance. You have a choice between commissioning three turbines with 90-meter blades and four turbines with 75-meter blades. They would generate roughly the same amount of energy (the four smaller machines would supply slightly more). But the four smaller turbines would reduce maintenance and obsolescence costs by 14% and require 18.5% lower (composite) material requirement for the blades. Put simply, the wind industry’s assumption that bigger is better might simply not be true.


While the parallel between wind farms and the oil rush example is already telling, our experiences with the electronics industry serve as another cautionary tale. Much like the wind energy industry, the electronics industry did not anticipate or plan for managing electronic waste, recycling of which turned out to be a major problem in the 2000s. When the European Commission’s WEEE Directive came knocking on the door, many electronic device producers realized that the EOL costs imposed by the directive would simply shave their already tight margins even further. Not surprisingly, local governments quickly realized that when producers could not handle the retroactive responsibility, the financial burden would fall on the taxpayer. More recently — and even more relevant — similarly overlooked environmental costs are accumulating in solar energy, as we have already documented previously in HBR. The burdens can be heavy. In Canada, for example, asset retirement in the oil and gas industry could leave taxpayers facing an estimated $72 billion in future liabilities.


Those who cannot remember the past are condemned to repeat it, as the saying goes. The pioneers of the Pennsylvania Oil Rush could not have foreseen the social and environmental toll their actions would take more than a century later. They were leaders of their time, operating under the scientific understanding and ethical paradigms of their era. But in the rush and excitement of our transition to renewable energy, we must not forget that environmental degradation takes many forms — and we need to learn to look beyond short-term clean energy gains if we are not to replace one form of environmental degradation with another.


source:Harvard Business Review (am Aflaki, Atalay Atasu, and Luk N. Van Wassenhove)

Faerch advances circular packaging leadership with growing rPET volumes from Cirrec

As many recyclers across Europe face significant market pressures and operational challenges, Faerch’s integrated recycling facility, Cirrec...