Today's KNOWLEDGE Share :: What is the glass transition in plastics, really not from a datasheet point of view, but from the polymer molecule and up?
Today's KNOWLEDGE Share What is the glass transition in plastics, really not from a datasheet point of view, but from the polymer molecule and up? Plastics soften, become rubbery or flow when used above their glass transition temperature (Tg). Below Tg, those same materials become stiff, brittle and glassy. Parts crack in cold environments. Impact resistance disappears. What worked fine yesterday suddenly fails today. The glass transition is the temperature range where molecular mobility becomes mechanically relevant. It is not a chemical change or a melting event. - The polymer does not melt. - No chemical bonds are broken. - The chemistry does not change. - There is no phase change. Tg arises from cooperative segmental motion: small segments of polymer chains start to move together, enabled by sufficient thermal energy and free volume. Below Tg, polymer chains are effectively locked in place, like a tangled ball of yarn. Stress is stored elastically, leading to brittle fracture. ...