New Technique to Improve Properties of Carbon Nanotube-based Fibers

The Lyding Group has recently developed a technique that can be used to build carbon-nanotube-based fibers by creating chemical crosslinks. The technique improves the electrical and mechanical properties of these materials.

Carbon nanotubes are strong and are very good at conducting heat and electricity. Therefore, these materials have wide applications and can be used as strong fibers, batteries, and transistors,” said Gang Wang, a postdoctoral research associate in the Lyding lab, which is at the Beckman Institute for Advanced Science and Technology at the University of Illinois at Urbana-Champaign.

New Method Based on Linking Individual CNTs Together


There are many ways to build materials that have carbon-nanotube-based fibers. “Airplane wings can be made, for example, by embedding these fibers in a matrix using epoxy. The epoxy acts as a binder and holds the matrix together.” said Joseph Lyding, the Robert C. MacClinchie distinguished professor of electrical and computer engineering and a Beckman faculty member.


However, combining the tubes to make such materials can lead to a loss in important properties. “We came up with a method to bring a lot of that performance back,” Lyding said. “The method is based on linking the individual carbon nanotubes together.

The researchers dispersed brominated hydrocarbon molecules within the nanotube matrix. When heat is applied, the bromine groups detach, and the molecules covalently bond to adjacent nanotubes.

When you pass current though these materials, the resistance to the current is highest at the junctions where the nanotubes touch each other,” Lyding said. “As a result, heat is generated at the junctions and we use that heat to link the nanotubes together.

The treatment is a one-time process. “Once those bonds form, the resistance at the junction drops, and the material cools off. It’s like popcorn going off —once it pops, that’s it,” Lyding said.

The researchers faced many challenges when they were trying to build these materials. “We have to find the right molecules to use and the proper conditions to make those bonds We had to try several times to find the right current and then use the resulting material to build other devices,” Wang said.

The paper is the first step in making a new class of materials. It is likely that the performance will become better because it has not been explored fully yet. The researchers are investigating how strong they can make these materials and improve their electrical conductivity and whether they can replace copper wires with materials that are 10 times lower in weight and have the same performance.
 

Source: Beckman Institute for Advanced Science & Technology
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