Monday, April 14, 2025

Today's KNOWLEDGE Share : mechanical properties of carbonized phenolic resins

Today's KNOWLEDGE Share

Effect of post-curing on the mechanical properties of carbonized phenolic resins

After curing, phenol-formaldehyde resins were post-cured at 160°C, 230°C, and 300°C in air for several hours, and then those post-cured samples were carbonized at 1000°C. The effect of post-curing on the physical properties and microstructure of the carbonized phenolic resin is reported in this article. The purpose of post-curing was to improve the mechanical properties of the carbonized resins. The post-curing process promoted the crosslinking reaction and the evolution of gases. The cured resin post-cured at a higher post-curing temperature (300°C) had a significantly higher weight loss, greater linear shrinkage and lower density than other samples. During carbonization the post-curing process not only decreased the weight loss but also limited the shrinkage. Post-curing also promoted the formation of carbon basal planes and the chemical densification in structures of the final carbonized resins. The increase in post-curing temperature and time had the effect of reducing the linear shrinkage of the resin during carbonization. The TGA thermal analysis showed that the post-cured resins improved the total weight loss more than 15 wt% over the unpost-cured resin. The carbonized resins developed from the post-cured resins had a greater flexural modulus by about 10–50% and improved the linear shrinkage by about 10% over that developed from unpost-cured resins.



source :Tse-Hao Ko, Tsu-Sheng Ma

#phenolicresin

Today's KNOWLEDGE Share : Svante August Arrhenius-Nobel Prize 1903

Today's KNOWLEDGE Share

Svante August Arrhenius-Nobel Prize 1903

This Swedish physical chemist is best known for his theory of electrolytic dissociation in aqueous solution, first presented for his doctorate thesis at the University of Uppsala when he was 24. The idea that oppositely charged ions resulting from dissociation of molecules could be present in the same solution initially met a hostile reception, but with support from Ostwald, van't Hoff and others the theory was gradually accepted.


Arrhenius was able to demonstrate the effect of electrolytic dissociation on osmotic pressure, lowering the freezing point, and increasing the boiling point of solutions containing electrolytes.


He then examined the relationship between toxins and antitoxins, their importance in relation to biological problems such as serum therapy, digestion and absorption, as well as gastric and pancreatic juices. The great importance of electrolytic dissociation theory is universally accepted today, even if some modifications have been found necessary.


Arrhenius also applied physicochemical principles to the study of meteorology, cosmology, and biochemistry. In meteorology, he predicted the scientific conclusion that increased concentrations of greenhouse gases in the atmosphere cause global warming.


Svante Arrhenius made important contributions to our understanding of the greenhouse effect and the role of greenhouse gases in Earth’s climate. In 1896, he published an article entitled “On the Influence of Carbonic Acid in the Air upon the Temperature of the Ground,”which suggested that the increase in carbon dioxide in the atmosphere caused by human activities could lead to global warming.

Arrhenius suggested that the carbon dioxide, water vapor and other gases in the Earth’s atmosphere acted like a greenhouse by trapping heat from the sun and preventing it from escaping back into space. He calculated that doubling the concentration of carbon dioxide in the atmosphere could raise global temperatures by up to 5-6 degrees Celsius.


He is also known for the Arrhenius Equation k = A exp -E/RT, which describes the effect of temperature on reaction rates. He was instrumental in establishing physical chemistry as a separate discipline. A man of eclectic scientific interests, he later published papers on immunology, cosmology and geology. He was awarded the 1903 Nobel Prize in Chemistry.


Source:turkchem.net/chemistry.msu.net

Follow: http://polymerguru.blogspot.com


#chemistry #electrolyte #greenhousegas #meteorology #

Transforming plastic waste into high-quality 3D-printed products

Every year, some 5.6 million metric tons of plastic packaging winds up in household waste in Germany after being used just once. So far, less than a third of it can be recycled. Working in partnership with Hochschule Bremen—City University of Applied Sciences, the Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM aims to transform this waste into high-quality 3D-printed products.


Volumes of plastic waste are rising, having approximately tripled across Germany over the past 30 years. Packaging waste in particular is a major contributor to this. Where German households produced 2.1 million metric tons of plastic waste in 1994, the figure had risen to 5.6 million by 2023. That makes it even more important to find ways to recycle these single-use products, most of which are based on crude oil.


"But it is much harder to recycle post-consumer waste than plastic residue left over from industrial production," explains Dr. Silke Eckardt, a professor focusing on sustainable energy systems and resource efficiency at Hochschule Bremen—City University of Applied Sciences (HSB). After all, these materials are not only highly heterogeneous but generally also dirty.


To close the production cycle nevertheless, HSB has teamed up with researchers at Fraunhofer IFAM to recycle even these tough-to-handle plastics from private households and then put them to use in additive manufacturing.

Recycled plastic used in filaments for 3D printing

"Since the waste is supposed to be recycled for use in 3D printing, it has to meet very stringent requirements for aspects such as purity, shape and size," explains Dr. Dirk Godlinski, a project manager in the Composite Technology working group at Fraunhofer IFAM.

To this end, the polypropylene output from a sorting plant for packaging waste was used in a feasibility study conducted by HSB and Fraunhofer IFAM.


To ensure sufficient purity, Eckardt and her team processed the sorting plant output further: At the university's Laboratories for Circular Economy, they ground up the plastic, washed it and separated undesired material from the mainstream using a float-sink-separation. The team used near-infrared technology to identify residual foreign plastics and removed them subsequently. After that, the researchers ground down the material again until it had reached the grain size required for compounding and dried it. This method achieved purity levels of more than 99.8%.

Then Fraunhofer IFAM took over: "In the project, we produced homogeneous polypropylene from the prepared waste," Godlinski says. "This is a versatile form of plastic that is durable, resistant to breaking and relatively flexible."

The research scientist and his team produced a solid plastic strand. First, they processed the flakes of recycled polypropylene in an industrial extruder at Fraunhofer IFAM. The material was combined there, mixed using different extruder screw geometries, then melted at temperatures greater than 200 degrees Celsius and extruded.


"The expertise consists in precisely adjusting the various mechanical screws, temperatures, pressures and speeds along the production process so the final product is homogeneous polypropylene," Godlinski explains. For further processing in 3D printing, for example, the strand must be round and consistent in diameter over its entire length, with a smooth surface.

The researchers succeeded in this: The gray plastic strand, about two millimeters thick, was able to be used directly as a filament in a commercial 3D printer. By now, Godlinski and his team have successfully printed their first components, including caps.

This marks the conclusion of the feasibility study by HSB and Fraunhofer IFAM. The researchers are now optimizing the production process. Ideas for follow-up projects have already been floated. Godlinski notes that plastics can be further refined, for example, by introducing additives such as glass fibers during compounding. This makes it possible to produce even very high-quality components for use in fields such as aviation and the automotive industry.


source : Fraunhofer Institute for Manufacturing Technology and Advanced Materials IFAM / Tech Xplore



Sunday, April 13, 2025

Today's KNOWLEDGE Share :Warpage & Shrinkage

Today's KNOWLEDGE Share

With glass fibers, shrinkage can be 10X lower in the flow direction than in the transverse direction.



This is the classical driving mechanism for warpage of GF filled compounds and most people will look at the ratio of perpendicular to parallel shrinkage as a sort of Warpage Index.


However, one can easily demonstrate that Warpage does NOT scale with this RATIO, but rather with the DIFFERENCE of perpendicular to parallel shrinkage.

This is crucial, because when you increase packing, you reduce both values (hence, their difference), but barely change the ratio.

And what we observe is that if you double the packing pressure, you roughly cut the warpage down by 50%, despite the anisotropy ratio remaining the same !

Packing is the single most effective way to reduce warpage in GF filled materials.


Credit:Vito leo

Saturday, April 12, 2025

Today's KNOWLEDGE Share : DELO releases IBOA-free medical adhesive for glucose monitoring sensors and other wearables

Today's KNOWLEDGE Share

DELO releases IBOA-free medical adhesive for glucose monitoring sensors and other wearables

DELO has released a new light-curing medical-grade adhesive engineered with nontoxicity in mind. DELO PHOTOBOND MG4047 is designed for wearable medical applications such as glucose monitoring sensors (CGM). Its chemical properties and impermeable characteristics help prevent skin irritation in cases of media influence such as rain or sweat.



With a 230-MPa Young’s modulus and a 200% elongation at tear while maintaining a 9-MPa compression shear strength, DELO PHOTOBOND MG4047 manages to be both a highly flexible and decidedly strong adhesive. These physical properties enable it to prevent common problems associated with wearable sensors such as sensor drift, which can occur following potting.


Chief among its advantages is that it is IBOA-free. IBOA, or isobornyl acrylate, is a chemical compound found in many polymer materials and is considered an extractable material. If medical wearables worn by patients are exposed to external media such as rain or sweat, tiny particles may leak out and contact the skin, causing adverse reactions such as irritation or allergies. Being free from IBOA reduces the risk of such reactions.

DELO PHOTOBOND MG4047 also demonstrates its nontoxicity through its biocompatibility, meeting the requirements outlined the DIN EN ISO 10993-5 cytotoxicity test. It complies with EU RoHS Directive 2015/863 as well, which is used to ensure nontoxicity in substances used in electronic equipment.


In addition to biocompatibility, #DELO PHOTOBOND MG4047 achieves low water absorption at 0.15 wt%, resulting in low water permeation at 13 (g·mm)/(m²·24h). This creates a high water vapor barrier and prevents potential contact with other leachable substances.

The curing properties of this light-curing #adhesive are optimized for mass medical wearable production with a required irradiation time of as little as two seconds under a 365–400-nm LED light with an intensity of 1000 mW/cm².


source:DELO


Friday, April 11, 2025

TYPE 4 COMPOSITE H2/CNG CYLINDER PROJECT REPORT

Newly added latest technological advancements in the composite cylinder manufacturing process and options on starting the project in the right direction to win the race in the global market.

This report is available on competitive pricing-Moving toward a user friendly and a safer environment.Let's understand the market before venturing into the business.

This report has covered the following topics:
■An overview landscape of the market
■Global Natural Gas Vehicles (NGVs) market
■ Latest technological advancements in Type 3/4 COMPOSITE H2/CNG Cylinder market
■ Merger & Acquisition
■ Major players share
■ Investment structure
■ Standards
■ costing and certification
■ Automotive Type 4 CNG/H2 Composite cylinder market in India and the rest of the world
■ Bulk transportation Type 4 CNG Composite cylinder market in India and the rest of the world
■ Swot analysis
■ The durability of the Type 4 Composite CNG cylinder
■ Initial Project cost to set up CNG/H2 manufacturing line
■ Strategic Model followed by the KEY PLAYERS
■ Economic efficiency & safety
■ The Future Trends in Composite CNG/HYDROGEN Cylinder market

The report provides up to 2024 of the Global Natural gas vehicle market. This will cover an overview of the market and what is happening in the Hydrogen and NGV market. The latest technological advancements will be shared in the report.

This report covers both vehicle and gas transportation and also states an estimate of the growth potential of the market.

Most of the leading players in each geographical region will be covered in detail and also my insights will be shared on each player and its market dominance

This report covers the International certification cost and the approximate cost of the cylinder. This report does not cover the breakdown of unit manufacturing costs Economic Efficiency will be focused in this report on the customer value proposition.
Current Hydrogen market and what is happening around the world in the Hydrogen economy. Hydrogen type 4 cylinders demand in various applications will be covered in the report.

The report will cover the initial investment cost of the manufacturing line and also cover the investment cost of larger and other options of investment that will favor the company/new entrant on this project.My aim is for the company to benefit from the report so it covers everything.

The main aim for preparing the report is to make the entrepreneurs/companies understand the difficulties of the project and what one should not follow when venturing this project. I do see many companies have started this project and struck in between their prototypes and certification. This report will give them clear route to success in the type 4 project.

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BASF showcases medical tubes and conveyor belt made with Elastollan® GMP certified TPU

At CHINAPLAS 2025, BASF will showcase medical tubes, and a conveyor belt made with a food contact (FC) grade of its Elastollan® Thermoplastic Polyurethane (TPU) material innovation. BASF’s TPU plant in Shanghai is now certified to produce the Elastollan FC grade according to Good Manufacturing Practices (GMP). This brings the production of BASF’s #Elastollan FC closer to customers in Asia Pacific.



“The GMP certification speeds up time-to-market of Elastollan FC grade to our customers in Asia Pacific. At the same time, it allows us to better serve our customers with optimized solutions to their specific technical requirements in Asia, as well as to capitalize on stricter food safety regulatory requirements globally,” said Rohit Ghosh, Vice President, Business Management #TPU, Performance Materials Asia Pacific, #BASF.

In addition to compliance with stringent food safety regulations, BASF’s Elastollan FC grade delivers superior performance across a wide range of applications, such as toys, food processing equipment (belt, hose, etc.) and medical devices.


GMP are guidelines ensuring products are consistently produced and controlled according to quality standards. Elastollan FC grade also complies with other major global food contact standards, including EU 10/2011 and FDA Regulation 21 CFR 177.2600.


source:BASF

SABIC further divests its European Petrochemical (EP) business and its Engineering Thermoplastics (ETP) business in the Americas and Europe

The Saudi Basic Industries Corporation (SABIC) today announced the signing of two strategic transactions to divest its European Petrochemica...