Tuesday, March 25, 2025

France hits hydrogen jackpot: World’s largest reserve valued $92 billion found

This discovery positions France to lead the charge in hydrogen production, boosting local economies

cientists in France have made a groundbreaking discovery that could transform clean energy production. Beneath the soil of Folschviller, in the Moselle region, researchers have uncovered an astonishing 46 million tons of natural hydrogen.

This unexpected find has the potential to reshape global energy strategies by providing a new source of carbon-free fuel.

The discovery was made by scientists from the GeoRessources laboratory and the CNRS while they were searching for methane. Instead, at a depth of 4,101 feet (1,250 meters), they found an enormous deposit of white hydrogen.

This form of hydrogen is naturally occurring and does not require industrial production, unlike green hydrogen, which is made using renewable energy, or gray hydrogen, which is derived from fossil fuels.


To put this discovery into perspective, the newly found deposit represents more than half of the world’s annual gray hydrogen production—but without the environmental costs. If extracted efficiently, this resource could provide a clean, low-cost energy solution that eliminates CO₂ emissions entirely. Media reports estimate the discovery’s value to be approximately $92 billion.


White hydrogen: A game-changer for clean energy:

For years, the hydrogen industry has faced two major challenges: the high cost of producing green hydrogen and the pollution caused by gray hydrogen. White hydrogen offers a solution to both problems. Since it already exists underground, it does not require energy-intensive processes like electrolysis, nor does it rely on fossil fuels.

If similar hydrogen deposits exist elsewhere, this could signal the beginning of a major shift in energy production worldwide. Countries that previously depended on expensive hydrogen production technologies may suddenly find themselves with a natural supply of this clean fuel.


source:Hydrogen Central

Machine learning enables customized plastics that could reduce environmental impact

About 100 million metric tons of high-density polyethylene (HDPE), one of the world’s most commonly used plastics, are produced annually, using more than 15 times the energy needed to power New York City for a year and adding enormous amounts of plastic waste to landfills and oceans.


Cornell chemistry researchers have found ways to reduce the environmental impact of this ubiquitous polymer found in milk jugs, shampoo bottles, playground equipment and many other things by developing a machine-learning model that enables manufacturers to customize and improve HDPE materials, decreasing the amount of material needed for various applications. It can also be used to boost the quality of recycled HDPE to rival new, making recycling a more practical process.


“Implementation of this approach will facilitate the design of next-generation commodity materials and enable more efficient polymer recycling, lowering the overall impact of HDPE on the environment,” said Robert DiStasio Jr., associate professor of chemistry and chemical biology in the College of Arts and Sciences (A&S).


source: Cornell University/ Lifeboat Foundation

Monday, March 24, 2025

Today's KNOWLEDGE Share : Mantis Shrimp Pack a Punch With the Force of a Bullet

Today's KNOWLEDGE Share

Mantis Shrimp Pack a Punch With the Force of a Bullet and They Don’t Get Hurt.

Mantis shrimp are powerful little crustaceans: With a single, strong punch, they can smash a shell with the force of a .22 caliber bullet, unleash a shockwave and even crack aquarium glass—all without hurting themselves.

Now, scientists have discovered how the colorful invertebrates use the power of physics as a shield. Their punching fist, called a dactyl club, has a protective structure with multiple layers that the team says might one day inspire impact-resistant gear for humans. Their findings were published in the journal Science last week.



“To repeatedly execute these high-impact strikes, the mantis shrimp’s dactyl club must have a robust protection mechanism to prevent self-damage,” explains Horacio Espinosa, an engineer at Northwestern University who co-led the study, in a statement. We found it uses phononic mechanisms structures that selectively filter stress waves.This enables the shrimp to preserve its striking ability over multiple impacts and prevent soft tissue damage.

The team of researchers tested a hypothesis that the peacock mantis shrimp’s resilience comes from the structure of its dactyl clubs. The outer part of the club is covered in layers of mineralized fibers that form a V-shaped herringbone pattern, giving it resistance. Underneath, corkscrew like bundles of fibers form what’s called a Bouligand structure, where the fibers fan out in different directions.


In 2015, researchers proposed that the Bouligand structure in the lower layer could filter out certain high-frequency shockwaves from the punch, preventing the damaging vibrations from traveling back into the mantis shrimp’s body. But scientists hadn’t proven it in the lab.It was mostly theoretical calculations.


So, the Northwestern researchers conducted various experiments to confirm the idea. They used lasers to analyze how stress waves travel through the mantis shrimp’s club and used high-frequency pulses to peer into the inner workings of the armor’s microstructure.

Their work revealed that the outer layer of herringbone fibers helps the club resist cracking from the strike, while the inner Bouligand structure can selectively absorb high-frequency stress waves that might otherwise harm the rest of the creature’s limb.


The findings highlight the potential of exploiting these natural designs for technological applications. The structure could inspire new designs for protective military and sports equipment, as well as impact-resistant coatings & improved materials for the aerospace industry.


While the study used 2D models of the shockwaves, more complex, 3D simulations are needed to fully capture how the club’s structure works. Designing aquatic experiments with state-of-the-art instrumentation would allow us to investigate how phononic properties function in submerged conditions.”


source:smithsonianmag.com

video source:You Tube


https://youtu.be/E0Li1k5hGBE

Today's KNOWLEDGE Share : Polyethylene Furanoate(PEF)

Today's KNOWLEDGE Share

Polyethylene Furanoate(PEF) : THE FUTURE OF BIOPLASTIC

In the diverse world of sustainable biopolymers, it's easy to get lost in the sea of options. We're not claiming to be the ultimate solution for every need, but we're proud of how releaf®'s PEF stacks up against other materials.


This chart compares PEF with rPET, PBS, PHA, and PLA across key performance indicators. While each material has its strengths, PEF shines in areas like barrier properties, mechanical strength, and recyclability.

We're newcomers built on decades of research, and we're excited to be part of the sustainability conversation.


Delivering high-performance, truly recyclable materials that meet the evolving needs of eco-conscious brands.


source:Avantium


#polymers #bioplastic #circulareconomy #avantium

Today's KNOWLEDGE Share : New techniques clarify recycled plastic, increasing their value

Today's KNOWLEDGE Share

Mellow the yellow : New techniques clarify recycled plastic, increasing their value

A team of University of Wisconsin-Madison engineers has developed a new solvent-based technique for removing stubborn pigments from recycled multilayer plastic packaging. The advance makes recycled plastic more commercially appealing—increasing its market value and moving the industry closer to “closing the loop” for recycled plastic.


The research, published in the March 14, 2025, issue of Science Advances, was led by postdoctoral fellow Tianwei Yan and PhD student Charles Granger, who work in the lab of George Huber, a professor of chemical and biological engineering at UW-Madison.

Plastic pollution is a major environmental and sustainability issue, with millions of tons of plastic produced from petroleum products entering landfills, waterways and oceans each year. Despite decades of research, plastic recycling is still very limited; only about 9% of plastic is recycled globally, with much of it downcycled into less valuable products.

New technologies, however, may help close the loop on recycling, producing high-quality recycled plastic just as good as fresh, “virgin” plastic. Since 2020, researchers at UW-Madison have made great strides in chemical recycling through a pioneering process called solvent-targeted recovery and precipitation (STRAPTM).


STRAP is particularly good at recycling colored multilayer, flexible plastics, which include food packaging like bags, pouches, wrappers and films. These types of plastic often incorporate multiple specialized layers that prevent moisture, seal out oxygen and improve strength. STRAP uses a series of solvent washes to dissolve each layer of plastic, which is then recovered and processed into near-virgin plastic. These films also contain a variety of color bodies that are put in by brand owners to market their products.

In recent years, Huber’s team has refined STRAP. However, the researchers found that the final plastic films they produced often had a yellowish hue to them. That tinge makes the recycled end product much less appealing to manufacturers, reducing the value of the plastic by more than half.


“To consumers, yellow might be a sign of age or degradation,” says Granger. “In these recycled plastics, that’s not the case. It’s just from pigments. But either way, it looks gross.”

That’s why Granger and Yan set out to discover why recycled plastic film produced via STRAP looked yellow, and what they could do about it. They first tested dozens of pigments, adding them individually to polyethylene, the plastic most used in flexible packaging, running them through the STRAP process to see if they caused the yellowing. Soon, they narrowed the culprit down to Yellow 12, a common organic pigment used to print packaging.

Most other pigments break down during STRAP processing and are removed by solvents or filtering. But elements of Yellow 12 survive the process, remaining in the solvents used to dissolve the plastic. In the final processing step, in which the recycled plastic is dried, the researchers found that evaporating solvents left behind the pigment in the plastic, causing a yellow sheen in the final product.


Armed with that knowledge, the team was able to come up with a method to get rid of the color. “The yellow pigment has a higher solubility in STRAP solvents than other types of plastic pigments due to its chemical structure,” says Huber. “So the first thing was to pick a solvent that has a lower solubility of that pigment. Then there are a couple of extra steps that really make that plastic come out crystal clear.”

Working with Chemical and Biological Engineering Associate Professor Reid van Lehn and his students, who have developed a sophisticated database of solvent-polymer solubility called SolventNet, the team found a solvent that minimized the solubility of the yellow pigment. Then, Yan and Granger added activated charcoal to the process to bind the color bodies and remove even more of the yellow before using a press to squeeze as much solvent as possible out of the recycled plastic. All of this resulted in clear plastic with no yellow detectable to the naked eye.


While making recycled plastic clearer might seem like it’s just fixing a cosmetic problem, Huber says it is a critical step in making plastics recycling economically feasible. “One of the biggest challenges with plastics recycling is contaminants, and one of the biggest issues is dealing with color,” he says. “Clear plastic is worth two to 10 times more than colored plastic. That’s because every company wants to have their special color or logo on their packaging. With clear plastic you can add that color. But color also makes it harder to recycle.”

Yan and Granger say they would like to use their methodology to remove other contaminants found in recycled plastics, including other problematic pigments, dirt and debris, and chemical contaminants like bromine and PFAS.


George Huber is the Richard L. Antoine Professor in chemical and biological engineering at UW-Madison. Reid Van Lehn is the Hunt-Hougen Associate Professor in chemical and biological engineering. This work was partially supported by a gift from Ross Annable.

Other UW-Madison authors include Kevin L. Sánchez-Rivera, Panzheng Zhou, and Styliani Avraamidou. Other authors include Steven Grey and Kevin Nelson of Amcor in Neenah, Wisconsin, and Fei Long and Ezra Bar-Ziv of Michigan Technological University in Houghton, Michigan.

This work was funded by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Bioenergy Technologies Office under Award Number DE-EE0009285 to G.W.H and DE-EE0010294.

Top image caption: Tianwei Yan (left) and Charles Granger have developed a method for removing yellow pigments from recycled plastic film, like the one Yan holds, greatly increasing their marketability.


source:University of Wisconsin-Madison


Today's KNOWLEDGE Share :Compression on steel will lead to changes in the mold cavity

Today's KNOWLEDGE Share

Based on consulting requests, I realize that a lot of people forget that huge forces are developed during the molding process, as a result of pressure levels exceeding often 1000 bar/100MPa.


That amounts to 1 metric Ton of equivalent force applied to each square cm of tool surface.

That is why clamp tonnage numbers are what they are of course.


But, no matter how good your steel or tool design is, metal will bend significantly when subjected to huge unbalanced forces.


And, even more surprisingly, for balanced forces, the cavity will expand by "compressing" the steel by quite a few microns !

You can run a quick FEA to check that, by applying 1000-2000 bar on a piece of steel.


Of course tubular shaped parts will readily see significant core shift problems as soon as flow is slightly unbalanced, since a differential of a few Tons-force can quickly appear if flow is not perfectly balanced. The problem here is, of course, that the more the core deflects, the more the unbalance grows. So it is a bad case of positive feedback leading to catastrophic results (unexpected weldlines in the thinned side towards which the core has been bent/pushed).


Don't underestimate the importance of these effects in molding.


While coupling Flow Analysis with stress analysis on the steel structure can supposedly model this, it is very challenging to describe the complex tool assembly. And such coupled approaches can be very challenging numerically. So, while core-shifting predictions are now quite standard, full tool deflections are usually neglected in simulations. And the clear tendency of steel compressibility to lead to overpack is never accounted for.


source:Vito Leo


#polymers #injectionmolding

Saturday, March 22, 2025

Orion S.A. signs supply agreement for tire pyrolysis oil with Contec S.A.

Orion S.A, a global specialty chemicals company, announced today it has signed a long-term supply agreement with Contec S.A., which will provide Orion tire pyrolysis oil to produce circular carbon black for tire and rubber goods customers.

The agreement with Warsaw, Poland-based Contec further enables Orion to diversify its sources of tire pyrolysis oil, commonly known as TPO.

“With the ConPyro® TPO supplied by Contec, Orion will be able to make large-scale volumes of circular grades of carbon black that will supply growing demand from the world’s leading tire and rubber goods producers,” Orion CEO Corning Painter said. “This is yet another way that Orion is accelerating the transition to a circular economy.”

TPO-based manufacturing is the only circular technology that is moving into industrial production to produce high-quality active carbon black. The process takes discarded end-of-life tires and exposes them to high temperatures to produce a feedstock Orion can convert into virgin carbon black.


Orion is the only company that has made circular carbon black from 100% TPO as a feedstock. The company has also demonstrated that its circular products can replace virgin carbon black in many applications.

“At Contec, sustainability is one of our core values. This partnership is a clear confirmation to the market that the industry is continuously evolving, and the circular economy is no longer just a vision for the future - thanks to collaboration with Orion, it is becoming a tangible reality today,” said Krzysztof Wróblewski, CEO of Contec S.A.


source: Orion S.A.

Today's KNOWLEDGE Share : We Cracked the Code: From Forever Waste to Circular Fibres

Today's KNOWLEDGE Share We Cracked the Code: From Forever Waste to Circular Fibres 90% fibre recovery. Safety standards exceeded. CO₂ em...