Saturday, September 21, 2024

Today's KNOWLEDGE Share : Improved process should accelerate tire recycling

Today's KNOWLEDGE Share

Improved process should accelerate tire recycling

Evonik wants to help make rubber materials from scrap tires easier to re-use in the manufacture of new automobile tires. So far, the suitability of recycled rubber has been very limited because its chemical structure hampers interaction with new tire materials. A team of researchers at Evonik has now made a key step forward with a process that could make it possible to use up to four times as much recycled rubber in new tires as in the past. “That brings us much closer to the key targets of sustainability and resource efficiency in this sector,” says Christian Mani, Project Manager Circularity at Evonik.



New tire rubber is normally produced by vulcanization of raw rubber, sulfur, and other components. When heat and pressure are applied, the sulfur forms bonds with the long carbon chains in the rubber, resulting in a robust, three-dimensional network. That is also the structure of ground tire rubber from end-of-life-tires. However, since the material has already been vulcanized, its properties differ from those of non-vulcanized rubber. Currently, trade associations in the tire recycling sector therefore set an admixture of about 5 percent ground tire rubber from end-of-life-tires as the upper limit.


Consequently, only small amounts of recycled rubber powder are re-used in the manufacture of new automobile tires at present. The majority of the recycled rubber is used, for example, in the production of protective elements for playgrounds and running tracks. In addition, many end-of-life-tires still undergo thermal reprocessing as fuels for energy generation. However, Mani is sure: “Rubber is far too valuable a raw material to be used only once in tires. We want to incorporate it into a circular system.”

He and his team of researchers have now succeeded in reversing the vulcanization of rubber to a large extent. “By adding a special formulation containing vinyl silanes, the firm bonds in the recycled rubber can be split. We cleave the sulfur bridges in the rubber, yet leave as many of the long carbon chains as possible untouched,

The research team has already used these vinyl silanes successfully for devulcanization. In trials, the proportion of recyclate in the rubber blend could be increased to up to 20 percent—compared with the technical threshold of around 5 percent outlined above.


The sustainability benefits of a circular solution of this type would be tremendous: Globally, there are more than 1.3 billion passenger cars. More than 2,000 new tires are produced every minute. There is no sign that demand will end—because even electric and hydrogen-powered automobiles will use rubber tires in the future. Annual global sales of tires for passenger cars amount to over €100 billion.


source:Evonik

Friday, September 20, 2024

Today's KNOWLEDGE Share : Wetting agents vs Dispersants

Today's KNOWLEDGE Share

What are the differences between wetting agents and dispersants?

Several types of additives can be used in the dispersion process in which solid particles, like pigments and fillers, are distributed and stabilised in a liquid.

Often two categories of additives, wetting agent (EU) and dispersants (EU), are mentioned in one breath. However, the two materials differ strongly with respect to the role they play in the system and with respect to chemical composition and morphology of the molecules they are composed of.


Functionality

It is important to have a clear view on what each raw material that is used in a paint or ink should do. The job a raw material, like an additive, must do in a system is called functionality.


Wetting agents:

Wetting is the first step in the dispersion process. The air that surrounds the solid particles in an agglomerate must be substituted by liquid. Wetting will take place when the surface tension of the liquid is low compared to the surface energy of the solid particles. Wetting will not occur when the surface tension of the liquid is too high. In that case, the surface tension of the liquid can be lowered by adding a wetting agent. A wetting agent does its job because the molecules adsorb and orient on the liquid-air interface.


Dispersants:

Solid particles attract each other. For this reason, energy is needed to separate the particles from each other in the second step of the dispersion process. Also, solid particles must be stabilised after they have been separated from each other. The particles will move to each other and glue together again when particle-particle repulsion is insufficient. The spontaneous process of gluing together solid particles in a liquid is called flocculation. The functionality of a dispersant is to prevent flocculation. Dispersants do their job because the molecules adsorb on the solid-liquid interface and assure repulsion between the particles.


Repulsion can result from two mechanisms that may either be used separately or in combination:

Electrostatic stabilisation: all particles carry a charge of the same sign.

Steric stabilisation: all particles are covered with tails dissolving in the liquid that surrounds the particles.


Source:essar.com



Thursday, September 19, 2024

Drinking water pressure pipes made from chemically recycled plastic installed in Vienna, Austria

Borealis is pleased to announce the success of a value chain collaboration to develop a chemically recycled drinking water pressure pipe. Around 660 meters of polyethylene PE100-RC (crack resistant) drinking water pressure pipes based on Borealis’ transformational Borcycle™ C technology platform are being laid in Vienna, marking a significant step forward on the path to a circular economy. The installation is the result of a pilot project to help Wiener Wasser (the Vienna Water Department), increase the sustainability of its operations.


The groundbreaking initiative is the outcome of an all-Austrian partnership between Borealis, Pipelife, a solution brand of wienerberger, and Wiener Wasser—a collaboration carried out in the spirit of EverMinds™, Borealis’ platform to accelerate the transition to a circular economy for plastics.

Creating drinking water pressure pipes from recycled plastic posed a significant challenge due to the high purity and quality requirements of materials used in sensitive and demanding applications. The breakthrough was made possible by Borcycle C technology, with which polyolefin-based waste is chemically recycled into new, virgin-quality plastics that are capable of meeting stringent performance standards. Mechanically recycled polyethylene and polypropylene do not yet meet the standards required for pressure pipe applications.


The specific grade, BorSafe™ Bc HE3490-LS-H-90, contains over 90% chemically recycled content, based on a mass balance allocation. This enabled the project partners to avoid a lengthy revalidation and reapproval process. The integrity of the approach is verified by ISCC PLUS certification (International Sustainability & Carbon Certification), which covers the entire supply chain, from raw material to final product, guaranteeing compliance with strict sustainability standards.


“This is an excellent example of how our infrastructure pipe solutions are enabling life’s essentials,” states John Webster, Borealis Global Commercial Director Infrastructure. “We have a long track record of providing innovative and advanced pipe solutions for the global infrastructure industry. In expanding our offering to include more sustainable solutions, we’re pleased to continue this legacy.”


The project also leverages the considerable experience of Pipelife, an international manufacturer of piping solutions, which is part of wienerberger, one of the leading providers of innovative, ecological solutions for the entire building envelope in the areas of new buildings and renovations, as well as infrastructure in water and energy management. As manufacturers of the PE100-RC drinking water pressure pipes, Pipelife benefitted from the fact that Borcycle C grades are a drop-in solution, processable on existing equipment.


source:Borealis

Wednesday, September 18, 2024

Today's KNOWLEDGE Share:TORLON (PAI)

Today's KNOWLEDGE Share

TORLON:

Torlon® polyamide-imide (PAI) is the highest performing, melt-processable thermoplastic. The amorphous polymer has exceptional resistance to wear, creep and chemicals and performs well under severe service conditions up to 260°C (500°F). Torlon® PAI also has superior electrical and structural characteristics at high temperatures, an extremely low coefficient of linear thermal expansion, and exceptional dimensional stability. Typical applications include non-lubricating bearings, seals, valves, compressors, and piston parts, bearing cages, bushings, and thrust washers.

Why Torlon® PAI?

Unsurpassed wear resistance in dry and lubricated environments

Maintains strength and stiffness up to 260°C (500°F)  

Very low-temperature toughness and impact strength

Excellent resistance to wear and creep under load

Resistant to most chemicals, including strong acids and most organics 

Excellent compressive strength and extremely low CLTE

Low flammability and smoke generation


Market Applications:

Parts made from Torlon® PAI polymers perform under conditions generally considered too severe for thermoplastics.

Typical applications include aircraft hardware and fasteners,

 automotive transmission and powertrain components, and oil & gas exploration and recovery equipment. The material’s excellent electrical insulating properties have made it a common choice for semiconductor fabrication and testing as well as electrical and electronic components.


Amide-imide (AI) powders are widely used in high-performance, non-stick, and corrosion-resistant coatings for a variety of other demanding industrial uses. 


source:syensqo




Sunday, September 15, 2024

Today's KNOWLEDGE Share : Packing Phase

Today's KNOWLEDGE Share

Understanding Shrinkage in Injection Molding: The Role of the Packing Phase

In injection molding, shrinkage is fundamentally linked to thermal expansion.


However, this relationship can become complex, especially when we factor in the "Packing Phase."


During this phase, we apply significant pressure to the molten material, allowing us to inject more grams of material into a predefined mold volume, assuming we disregard mold deformation for now.

As a result, the final shrinkage can vary widely—ranging from high shrinkage, dictated by the room pressure PvT curve (in cases where no packing is applied), to even negative shrinkage in situations of overpacking.


While the basic principles of shrinkage are driven by Coefficient of Thermal Expansion (CTE), the reality is much more nuanced.


For instance, with glass-filled polymers, increased packing pressure can influence the anisotropy-driven warpage of the material; it may even suppress warpage without affecting the CTE anisotropy itself.


source:Vito leo

Saturday, September 14, 2024

Today's KNOWLEDGE Share :TOP PERFORMING HEAT RESISTANT PLASTICS

Today's KNOWLEDGE Share

TOP-PERFORMING HEAT RESISTANT PLASTICS

There are numerous types of heat resistant plastics available, each of which has unique advantages and disadvantages that make it suitable for different applications.



Some of the top-performing ones are:

PTFE (polytetrafluoroethylene). PTFE—commonly known by the brand name Teflon™—is characterized by its low coefficient of friction and high chemical resistance. It also demonstrates excellent flexural strength, electrical resistance, weather resistance, and thermal stability.It is suitable for use

in temperatures ranging from -328° F to 500° .


PEEK (polyetheretherketone). PEEK is a high-performance engineering thermoplastic with a semi-crystalline structure. It is resistant to chemicals, creep, fatigue, heat, and wear and has the highest flexural and tensile strength of any high-performance polymer. These qualities make it a suitable alternative to metals as they allow the material to remain strong and adaptable in harsh environmental conditions. It is suitable for continuous operating temperatures up to 500° .


PEI (polyetherimide). PEI—commonly only by the brand name Ultem®—is one of a handful of commercially available amorphous thermoplastics. It is strong, chemical resistant, and flame resistant and has the highest dielectric strength of any high-performance thermoplastic. It is suitable for continuous service temperatures up to 338°.


TYPICAL APPLICATIONS OF HEAT RESISTANT PLASTICS:

Heat resistant plastics are available in many forms, such as heat resistant plastic sheets. These various material forms are used to manufacture parts and products for a wide range of industries.


For example:

They are used for heat and shock resistant components in the aerospace, automotive, and glass industries.

They are used for heat resistant, emission proof, highly insulating, or defined conducting components in the electrical and semiconductor industries.

They are used for sterilization and hydrolysis proof components for the medical device industry.


They are used for emission proof and radiation resistant components for the nuclear energy and X-ray technology industries.

They are used for various components in the chemical industry.


source:newprocess.com

Thursday, September 12, 2024

Today's KNOWLEDGE Share : Fungal Mycelium as the Basis for Sustainable Products

Today's KNOWLEDGE Share

Fungi have more to offer than meets the eye. Their thread-like cells, which grow extensively and out of sight underground like a network of roots, offer huge potential for producing sustainable, biodegradable materials. Researchers at the Fraunhofer Institute for Applied Polymer Research IAP in Potsdam Science Park are using this mycelium to develop a wide range of recyclable products, from wallets and insulation to packaging.



Fungal Mycelium as the Basis for Sustainable Products:

To most of us, fungi look like a curved cap and a stem. However, the largest part of the organism consists of a network of cell filaments called mycelium, which mainly spreads below ground and can reach significant proportions. This finely branched network has been underutilized until now. However, for researchers at the Fraunhofer Institute for Applied Polymer Research IAP in Potsdam, mycelium represents a pioneering raw material with the potential to replace petroleum-based products with natural, organic mycelium composites. Organic residues from regional agricultural and forestry activities are used as the substrate for the fungal cultures. In various projects, the researchers are using mycelium-based materials to produce insulation, packaging, and animal-free alternatives to leather products.


Mycelium-based materials from regional agricultural residues:

“Faced with climate change and dwindling fossil raw materials, there is an urgent need for biodegradable materials that can be produced with lower energy consumption,” says Dr. Hannes Hinneburg, a biotechnologist at Fraunhofer IAP. Together with his team, he is using mycelium — for instance, from edible mushrooms or bracket fungi such as the oyster mushroom or tinder fungus — to transform locally available plant residues into sustainable materials. “The mycelium has properties that can be used to produce environmentally friendly, energy-efficient materials, since the growth of the fungi takes place under ambient conditions and CO2 remains stored in the residues. When cellulose and other organic residues decompose, a compact, three-dimensional network forms, enabling a self-sustaining structure to develop,” explains Hinneburg. This produces a material that is a complex compound with an organic substrate such as cereal residues, wood chips, hemp, reeds, rape or other agricultural residues. These substances are a source of nutrients for the fungus and are permeated entirely by a fine network of mycelia during the metabolic process. This produces a fully organic composite that can be made into the required shape and stabilized through thermal treatment. “First, you mix water together with agricultural residues such as straw, wood chips and sawdust to form a mass. Once the level of humidity and particle size have been determined, and the subsequent heat treatment to kill off competing germs has been completed, the substrate is ready. It provides food for the fungi and is mixed with the mycelium. Following a growth phase of around two to three weeks in the incubator, the mixture will produce, depending on the formulation and process used, a substance similar to leather or a composite that can be processed further,” says Hinneburg, summarizing the production process. No light is required for this process — a bonus as far as energy efficiency is concerned.


Versatile applications: 

strength and elasticity can be specifically configured The fungal materials can be cultivated with a wide range of properties. Depending on the application, they can be hard-wearing, stretchable, tear-resistant, impermeable, elastic, soft and fluffy, or open-pored. The result is determined by the combination of the type of fungus and agricultural residues, plus variable parameters such as temperature and humidity. The duration of mycelial growth also influences the end product. The versatility of the material means it can take on a huge variety of forms, from thick blocks to wafer-thin layers, and be used in a multitude of scenarios. This makes it possible to use fungi-based materials for textile upholstery, packaging, furniture, bags or insulation boards for interiors. When used as a construction material, the fungus primarily functions as a biological adhesive since a wide range of organic particles are joined together via the mycelium.

“The many positive properties of the material, heat-insulating, electrically insulating, moisture-regulating and fire-resistant, enable an important step toward circular and climate-positive construction,” says Hinneburg, one of whose current projects involves developing a novel polystyrene alternative for thermal insulation. In another project, he is working alongside the Institute for Food and Environmental Research and Agro Saarmund e.G. to produce environmentally friendly, mycelium-based packaging trays from residues and raw materials sourced from local agricultural and forestry activities. In work he has done with designers, he has also developed the base material for animal-free alternatives to leather products such as bags and wallets. As the mycelium-based materials look similar to their leather counterparts, they can be used to complement leather items in certain areas.

Developing industrial processes

In Europe, only a few companies are currently developing mycelium-based materials for commercial use. The challenges in this area include access to biogenic residues, the ability to ensure consistent product quality and the means to scale up activities efficiently.

To address these challenges, the researchers are using a newly developed roll-to-roll method, for which they have already created a prototype. This method offers significant advantages over standard manufacturing processes involving boxes and shelving systems: By using a standardized, continuous production method under controlled process conditions (such as temperature and humidity), the researchers can ensure that the mycelium-based products have consistent material properties. What’s more, resources can be used more efficiently, and production can be scaled to an industrial level. “This is crucial in order to meet growing industry demand for sustainable materials and to become less dependent on petroleum in the long term. Production can also be improved further by using innovative technologies such as artificial intelligence to optimize the combination of residues and types of fungi,” says Hinneburg.


Source: Fraunhofer-Gesellschaft



Today's KNOWLEDGE Share : More sustainable epoxy thanks to phosphorus

Today's KNOWLEDGE Share More sustainable epoxy thanks to phosphorus Epoxy resin is a clear, robust polymer that is widely used – especia...