Thursday, February 22, 2024

Today's KNOWLEDGE Share:Mold compression changes cavity by few microns in Injection molding

Today's KNOWLEDGE Share

Based on consulting requests, I realize that a lot of people forget that huge forces are developed during the molding process, as a result of pressure levels exceeding often 1000 bar/100MPa.


That amounts to 1 metric Ton of equivalent force applied to each square cm of tool surface.

That is why clamp tonnage numbers are what they are of course.


But, no matter how good your steel or tool design is, metal will bend significantly when subjected to huge unbalanced forces.


And, even more surprisingly, for balanced forces, the cavity will expand by "compressing" the steel by quite a few microns !

You can run a quick FEA to check that, by applying 1000-2000 bar on a piece of steel.


Of course tubular shaped parts will readily see significant core shift problems as soon as flow is slightly unbalanced, since a differential of a few Tons-force can quickly appear if flow is not perfectly balanced. The problem here is, of course, that the more the core deflects, the more the unbalance grows. So it is a bad case of positive feedback leading to catastrophic results (unexpected weldlines in the thinned side towards which the core has been bent/pushed).


Don't underestimate the importance of these effects in molding.


While coupling Flow Analysis with stress analysis on the steel structure can supposedly model this, it is very challenging to describe the complex tool assembly. And such coupled approaches can be very challenging numerically. So, while core-shifting predictions are now quite standard, full tool deflections are usually neglected in simulations. And the clear tendency of steel compressibility to lead to overpack is never accounted for.


Source:Vito Leo


 #injectionmoulding #polymers

Wednesday, February 21, 2024

Today's KNOWLEDGE Share :The Long-Term Costs of Wind Turbines

Today's KNOWLEDGE Share

The Long-Term Costs of Wind Turbines

In 1859, the town of Titusville in Pennsylvania vaulted into the limelight when Edwin Drake struck oil, thereby marking the inception of America’s oil industry. With an initial depth of 69.5 feet (roughly equivalent to the blade size of a 0.5 MW wind turbine), Drake’s well set the stage for an unprecedented era of economic prosperity.


Companies and workers alike descended upon Pennsylvania’s black-gold frontier, applying rudimentary cable-tool drilling technology to tap shallow reserves. However, as these reserves ran dry, the industry underwent a transformation. With improvements in technology and a better understanding of the geology of oil reservoirs, operators began to go deeper. Rotary drilling techniques, which were more effective than the earlier percussion methods, were introduced and made deeper drilling more feasible. Additionally, improvements in pumping technology enabled oil to be extracted more efficiently from greater depths.


For a while, it seemed like the fountain would flow endlessly. But eventually, Pennsylvania began to run out of extractable oil. Newer and more promising fields were discovered elsewhere, drawing attention and resources away from older sites. But in the absence of regulations, operators simply abandoned their wells without properly capping or decommissioning them. The result is that today Pennsylvania is plagued by more than 8,800 “ghost wells”: abandoned oil wells that continue harming the environment and local communities. Emitting methane and leaking chemicals into groundwater, these wells degrade soil and make land unusable, stalling local development plans and reducing property values.


The development of the turbine industry is eerily reminiscent of Pennsylvania’s forgotten oil rush. In 2021, global wind capacity increased by 94 GW, primarily led by six countries: the United States, China, Germany, India, Spain, and Brazil. This growth in wind power has been accompanied by dramatic cost reductions, making wind energy increasingly competitive. Onshore wind energy costs fell by 68% and offshore by 59%, with 2021 seeing further declines of 15% and 13%, respectively. Over the decade from 2010 to 2021, onshore wind capacity increased four-fold, while offshore capacity grew 11-fold.


Much of this growth has come from making the turbines bigger. Bigger blades on turbines located farther offshore capture wind more efficiently, require fewer turbines for the same output, and offer more consistent energy generation due to steadier offshore winds. These factors also reduce the costs associated with integrating the energy output with national grids. Keen to accelerate this trend, governments around the world offer various financial incentives. France, for example, subsidizes long-term wind-power purchase contracts and supports research and development programs aimed at enhancing the efficiency and cost effectiveness of offshore wind technology.


Unfortunately — and ironically — it also looks like the wind energy business could be repeating the mistakes of the Pennsylvania oil drillers, leaving the public with a legacy that is equally challenging for society. A rush to create power-generation capacity without a comprehensive approach that considers the entire lifecycle of wind farms can result in detrimental consequences for both the environment and the long-term viability of these projects. To ensure the long-term sustainability and viability of wind energy projects, designers and decision-makers should account for various factors throughout the entire lifecycle of a wind farm, including environmental impact and lifecycle costs: capital expenditures, operational expenditures, and end-of-life (EOL) costs.


As larger wind energy projects venture farther offshore to harness more consistent and powerful winds, a proportional escalation in costs across various categories is inevitable. Capital expenditures are not merely a factor of turbine costs; they also encompass the expenses associated with creating robust and durable offshore platforms, marine logistics, and extensive undersea cabling to connect these distant turbines back to the grid onshore. Operational expenditures also see a marked increase due to the complexity and challenge of routine maintenance and repair work in offshore conditions. These tasks become difficult and expensive as the distance from shore increases, often requiring specialized vessels and equipment, not to mention the increased risks that workers will face.


The most significant cost escalation is likely to occur in decommissioning, a complex and expensive endeavor involving the disassembly of turbines, removal of foundations and cables, reverse logistics of moving the blades and towers back to shore, and responsible waste management. Most economic analyses on wind farm design, however, assume that these costs will be negligible or diminish over time. They also underestimate maintenance costs, which are well known to increase over time. Moreover, they do not explore the implications of building larger turbines situated farther offshore on decommissioning and maintenance costs, which are typically set arbitrarily at 50% of the cost of making the turbine.


The industry cannot afford to brush over decommissioning and maintenance issues any longer. Through 2023, turbine operators such as Siemens Energy have incurred rising upkeep costs. (Shares in Siemens plunged 30% after the company announced it would have to spend an additional $1 billion in turbine maintenance.) The first major wave of decommissioning is also imminent, with around 34,000 onshore turbines close to retirement. Awareness of the problem is growing, triggering initiatives like the ZEBRA consortium in Europe, a research program that seeks to design a 100% recyclable wind turbine, while in the U.S., the State of Colorado now mandates the removal of decommissioned wind turbines.


In an effort to understand the economic implications of wind farm maintenance and decommissioning, we collected accessible wind farm data to estimate the construction cost of a single turbine as a function of its blade size and shore distance. We then estimated the total cost by assuming maintenance and end-of-life costs (MEOL) to be a fraction of construction costs and combined these estimates with physical principles of wind generation based on engineering equations involving wind speed distribution, energy generation, and other relevant factors to build a “lifetime value” model, which reveals the relationships between blade size, distance from shore, and turbine lifetime value (the total revenue generated from electricity produced by a turbine minus its total lifecycle cost), as depicted in Figure 1.


As the figure shows, larger turbines are, up to a point, more efficient, absent other factors (chart A). But that efficiency varies with shore distance (chart B), and the optimal blade size is clearly affected by the level of MEOL costs (the apexes of the curves in both parts move leftwards). We can conclude, therefore, that smaller blades can be better suited for farther offshore projects. In other words, suppose that you are considering the construction of a wind farm 35 km shore distance. You have a choice between commissioning three turbines with 90-meter blades and four turbines with 75-meter blades. They would generate roughly the same amount of energy (the four smaller machines would supply slightly more). But the four smaller turbines would reduce maintenance and obsolescence costs by 14% and require 18.5% lower (composite) material requirement for the blades. Put simply, the wind industry’s assumption that bigger is better might simply not be true.


While the parallel between wind farms and the oil rush example is already telling, our experiences with the electronics industry serve as another cautionary tale. Much like the wind energy industry, the electronics industry did not anticipate or plan for managing electronic waste, recycling of which turned out to be a major problem in the 2000s. When the European Commission’s WEEE Directive came knocking on the door, many electronic device producers realized that the EOL costs imposed by the directive would simply shave their already tight margins even further. Not surprisingly, local governments quickly realized that when producers could not handle the retroactive responsibility, the financial burden would fall on the taxpayer. More recently — and even more relevant — similarly overlooked environmental costs are accumulating in solar energy, as we have already documented previously in HBR. The burdens can be heavy. In Canada, for example, asset retirement in the oil and gas industry could leave taxpayers facing an estimated $72 billion in future liabilities.


Those who cannot remember the past are condemned to repeat it, as the saying goes. The pioneers of the Pennsylvania Oil Rush could not have foreseen the social and environmental toll their actions would take more than a century later. They were leaders of their time, operating under the scientific understanding and ethical paradigms of their era. But in the rush and excitement of our transition to renewable energy, we must not forget that environmental degradation takes many forms — and we need to learn to look beyond short-term clean energy gains if we are not to replace one form of environmental degradation with another.


source:Harvard Business Review (am Aflaki, Atalay Atasu, and Luk N. Van Wassenhove)

Tuesday, February 20, 2024

Today's KNOWLEDGE Share:Kevlar 29 Vs Kevlar 49

Today's KNOWLEDGE Share

Kevlar 29 vs Kevlar 49

Kevlar® 29 is used in the manufacture of body armour (panels) for lightweight military vehicles. A good example is the US Army’s ‘Bradley Fighting Vehicle’. This has been used extensively in Iraq and Afghanistan. Kevlar® 29 was selected for its armour, because it is lightweight and withstands attack from RPGs. The Kevlar® 29 panels protect the soldiers inside the vehicle.



Kevlar® 29 is ideal because it is lightweight and non-flammable and it offers protection from high temperatures (fire bombs, Molotov cocktails etc...). Kevlar® 29 can also withstand the harsh environmental conditions, found in hot climates.


Kevlar® 49 is used for specialist boat hulls and in the aerospace industry. It is popular as a material for boats because it is lightweight and can withstand a considerable amount of force (torque - twisting force), tensile stress and impact. Hulls manufactured from traditional materials, such as fibreglass, are limited in their resistance to forces and stress. Also, a lightweight boat is faster on the water and uses less fuel to complete distances.



Eurofighter is relatively light compared to other similar fighter jets, due to the selection of Kevlar ® 49 as a material in its manufacture. This means that it can fly faster and further, before in-flight refuelling is needed. It is more agile than its rivals due to excellent force (torque - twisting force) and tensile stress resistance. The plane is more likely to survive being hit by small arms fire, compared to other fighter planes, as Kevlar ® 49 has excellent impact resistance. 


FURTHER ADVANTAGES OF USING KEVLARKevlar® has a range of advantages, not only its relative low weight and high strength:


Laminated Kevlar® is very stable at high temperatures and it is impact and scratch resistant.


Kevlar® is often combined with other materials, to produce textiles with enhanced properties, such as fire resistant clothing for the Fire Services.


Kevlar is used in some quality walking boots because it is waterproof (when combined with other materials as a composite) but also breathable, ensuring comfort.


When Kevlar is used as a composite with rubber, it retains its flexibility. This composite material is used in the manufacture of Formula One Racing Car petrol tanks. The tank holds the petrol safely, even in the event of an accident. The material cannot be pieced by other car components, even during a high speed impact. The petrol does not escape / leak, avoiding fire and explosions. The lightweight tank, adds to the reduced weight of the entire vehicle, leading to a faster racing car.


source:technologystudent/heaterk



Monday, February 19, 2024

3D printing technology for tissue: Bayreuth researchers combine hydrogels and fibres in a new technology

Prof. Dr Leonid Ionov and his team at the University of Bayreuth have developed a new type of 3D printing technology that combines hydrogels and fibres. The innovative process, combined in one device for the first time, enables the production of constructs with fibrous structures and uniaxial cell alignment. The research results, published in the journal “Advanced Healthcare Materials”, harbour potential for the artificial production of biological tissue.



Biofabrication, a specialised field of medical technology that deals with the production of biologically relevant structures, aims to replicate the complex architecture of human tissues and organs. One promising approach to counteracting the global shortage of donor organs is the use of 3D (bio) printing, an advanced biofabrication technique.


This technology was integrated, in a single, with a fiber spinning technology called touch-spinning. This approach has been under development at the University of Bayreuth since 2018 and enables the production of tissue-like structures. An innovative device for this has now been invented and patented in Bayreuth and could represent a significant advance in the production of living tissue. In addition, great progress has been made in the area of efficient production of fibres and composites.


In the latest study by Prof Dr Leonid Ionov, Professor of Biofabrication, and his team at the University of Bayreuth, various types of hydrogels were extensively tested for the 3D printing of tissues. A hydrogel is a water-retaining and at the same time water-insoluble polymer. In addition, the cell containing-hydrogels, also known as bioink, are combined with fibres to create a composite material. This is achieved by using 3D (bio) printing with an integrated touch-spinning process.


Touch spinning is a scalable process for producing of fibres from a polymer solution or melt. The Bayreuth scientists have now combined 3D (bio) printing technology with touch-spinning technology in a single device for the first time.

“The insights gained in this study are of great importance for the production of tissues and in particular tissues with fibrous structures and uniaxial alignment of cells such as connective and muscle tissue,” explains Prof. Dr Leonid Ionov.

In an article recently published in the journal “Advanced Healthcare Materials”, the Bayreuth researchers Prof. Dr. Dr. Elisabetta Ada Cavalcanti-Adam, Chair of Cellular Biomechanics, Prof. Dr. Leonid Ionov, Professor of Biofabrication, Waseem Kitana, PhD student at the Chair of Biofabrication, and their colleague Dr. Victoria Levario-Diaz from the Max Planck Institute for Medical Research, report on a novel approach for the production of multilayer bioink fibre composites.


source:AM Chronicle

Sunday, February 18, 2024

Today's KNOWLEDGE Share:Polydicyclopentadiene (pDCPD)

Today's KNOWLEDGE Share

Polydicyclopentadiene (pDCPD)

Polydicyclopentadiene (pDCPD) is a relatively new polymer which is formed through Ring opening metathesis polymerisation (ROMP) of  Dicyclopentadiene (DCPD).

pDCPD is a custom-engineered thermoset polymer designed to deliver an excellent combination of chemical, corrosion, and heat resistance, plus stiffness and impact strength. This material blends the molding flexibility of a thermoset with the high-performance characteristics of top engineering thermoplastics. It has a heat deflection temperature of up to 120°C.


pDCPD is unique because it has virtually no part size or weight limitations — parts with variable wall thicknesses, molded stiffening ribs, and more won’t slow down production. pDCPD is a relatively new material and its applications are limited as of yet, but it’s shown promise in corrosion-resistant chemical process equipment, septic tanks, and water treatment equipment.


Equipment

DCPD resins are transformed using high pressure RIM equipment as used in the polyurethane industry, with some small changes to be considered. As a reference, a widely used machine to inject DCPD resins is the Cannon A-100 fitted with a DCPD kit. The most important change is that the resin can never be in contact with air or moisture, which required a nitrogen blanket in the tanks. The tools or moulds are closed tools and are being clamped using a hydraulic press. Due to the fact that the resins shrink about 6% in volume during reaction, these presses (also called clamping units) don't have to handle high pressures such as for Sheet Moulding Compound (SMC) or expanding polyurethane.


Advantages of pDCPD:

Combines chemical, corrosion, and heat resistance

No part size or weight limitation – won’t slow down production

Blends molding flexibility with high performance


Disadvantages of pDCPD:

New material: applications are limited


Applications:

Since pDCPD is still a young material, the number of applications is quite limited. The major success story is in the field of body panels, mainly for tractors, construction equipment, trucks and buses. In the industrial applications, the main success story is components for chlor-alkali production (e.g. cell covers for electrolyzers). Other applications can be developed where impact resistance in combination with rigidity, 3D design and/or corrosion resistance is required.


source:telene

Friday, February 16, 2024

Evonik launches VISIOMER® HEMA-P 100

With the launch of VISIOMER® HEMA-P 100, Evonik introduces a Phosphate methacrylate monomer that improves adhesion, reduces corrosion, and provides flame-retardancy.


VISIOMER® HEMA-P 100 can act as a dispersant and complexing agent. Incorporated by polymerization, HEMA-P is non-migratory, and the effects are long-lasting. It can act as a dispersant and complexing agent.

Incorporated by polymerization, HEMA-P is non-migratory, and the effects are long-lasting.


Typical product applications of VISIOMER® HEMA-P include adhesives, coatings, construction and composites:


*In acrylic dispersions​, HEMA-P acts as an adhesion promoter & anti-corrosive agent (e.g. DTM)


*In structural acrylic adhesives, HEMA-P increases adhesion to polar substrates and improves corrosion resistance


*In emulsions for wood, textile or paper coatings, HEMA-P enhances the flame-retardancy


*To cast PMMA, HEMA-P brings flame-retardancy without compromising transparency or mechanical properties


VISIOMER® HEMA-P stands out due to its high monoester content which helps ensure maximum performance.

VISIOMER® HEMA-P is also available in a low viscosity 70% solution in MMA for easier handling. VISIOMER® HEMA-P 70M and the new VISIOMER® HEMA-P 100are available globally.


sourc:Evonik/jeccomposites

Thursday, February 15, 2024

Today's KNOWLEDGE Share:Dynamic Rheology

Today's KNOWLEDGE Share

I praised the incredible power of Dynamic Rheology to study polymer flow behaviour and the polymer molecular structure.


To be totally fair, I have to also acknowledge the equally valuable power of Dynamic Mechanical Analysis (DMA or DMTA).

The principle is strictly the same, with an in-phase and out of phase response. The test is however conducted on solid samples (tension, torsion, bending...) and is most useful in a Temperature sweep approach, ideally from cryogenic temperatures up and above Tg.


The data produced (in addition to the Tg value) can help assess the damping characteristics of the polymer for NVH aspects for instance.

The observation of multiple sub-Tg transitions is of great spectroscopic interest to understand molecular motions and segmental movements. These transitions are the key reason for toughness observed below Tg in many polymers, a performance aspect we rely upon everyday in our plastic parts.

Subtle plasticizing or anti-plasticizing mechanisms can be studied, highlighting often dramatic changes in mechanical performance with addition of a few tenth percent of additives or just due to moisture.


source:Vito leo

The BIOVALSA project: making bioplastics from agricultural waste and pruning residues

Every year, the Valencian agricultural sector generates around 800 000 tons of plant waste, such as rice straw and citrus pruning waste. The...