Evonik's Biobased VESTAMID® Terra PA Used in Multi-layer Tube Systems of Racing Car

RED Motorsport's Lotus Exige completed the third race of the new season on June 14th and 15th, took place in the Touring Car Championships (TCC) of the Deutscher Motorsport Verband (DMV) at the Hockenheimring. The racing car, which Evonik uses to test new applications, boasts a number of novel features this year including a multi-layer line for charge-air cooling. The green section of the line has an outer layer of a biobased polyamide, VESTAMID® Terra. This is the first time Evonik Industries is testing the multi-layer tube system with the biobased plastic on the race track. 

Since 2007, Evonik has been testing coolant line systems consisting of multi-layer tubes of petroleum-based VESTAMID® under tough racing conditions. These multi-layer tubes serve as lightweight replacements for rubber hoses and reinforced lines. The MLT 8000 multi-layer tubing system has since proven its performance in vehicles worldwide. The racing car of the current season uses MLT 8000.3 with an orange outer layer. This system is around 870 g lighter than cooling line systems with steelflex tubes, which means a weight reduction of more than 70 percent. 

The coolant lines of the 8000 series have three layers: The inner layer consists of a polypropylene specially adapted for this application. On top of this is an adhesion promoter layer, followed by the outer layer consisting of the high-grade specialty polyamide VESTAMID® or the biobased VESTAMID® Terra. 

Evonik's biobased polyamides have also been successful in other applications. They have been used commercially since 2010 as mono-layer tubes in, for example, air brake lines of utility vehicles, in semitrailers and trailers, and for pneumatic lines. The use of the biobased material in multi-layer tubing systems for coolant lines is new, however. 

Under the VESTAMID® Terra brand name Evonik offers various biobased polyamides (PA610, PA1010, and PA1012) covering a wide application spectrum that is used in hydraulic lines, for example. In road vehicles these lines are connected by means of quick connectors made from a petroleum-based, glass-fiber-reinforced polyamide 12 such as VESTAMID® L-GF30 or biobased VESTAMID® Terra HS1850. In racing vehicles, on the other hand, connection is by metal plug-in couplings. 

For many years, Evonik Industries has been making components specifically for the Lotus Exige to test them under the high demands imposed by motor racing. The findings flow into commercial-scale production — and not only in the automotive industry. 

Source:Evonik 

Metabolix to Explore Versatility of Biobased PHA Modifiers for Enhanced PVC Plasticization

New materials have long been sought that help to tackle increasing concerns about the future sustainability of petroleum feedstocks and the increasing generation of waste (and litter) driven by our growing population. Reducing generation by using less, for example in packaging, and recycling and reusing materials that often end up as waste, are both great places to look to creatively apply these new materials.

PVC (polyvinyl chloride) is one of the best known, versatile plastics in the world and one of the least recycled. PVC has qualities that make it usable in everything from piping and construction to signs and packaging.

However, PVC always requires additives before it can be made into a finished product and most of these additives, along with the PVC itself, are not made with renewable resources. Furthermore, while these additives provide important enhancements to the basic PVC polymer — from making the PVC more flexible to increasing its UV stability for outdoor use — they can hinder recycling and reuse. Many additives, like phthalates, unfortunately also migrate to the surface, out of the PVC, over time reducing the desired performance.

At Metabolix, we are researching the benefits of using our biopolymers as PVC modifiers to solve some of these problems, while improving performance and lowering overall formulation costs. Recent work led by Dr. Yelena Kann and presented at ANTEC 2013 entitled "Versatile Vinyl Plastic: Formulating for the future", highlighted how PHA modifiers offer PVC formulators with effective biobased impact modification. Data presented demonstrate that incorporation of these modifiers also does not compromise transparency nor UV stability of the PVC.

In December 2012, we introduced I6001, the industry's first biobased polymeric impact modifier for PVC to improve toughness and simultaneously impart some plasticization. The additional plasticization allows for elimination of some secondary plasticizers and for a reduction in the use of primary phthalates and other additives.

Unlike phthalates and some biobased plasticizers, our PHA modifiers bring plasticization without unwanted migration to the surface over time and resultant loss of toughness.

PHA polymeric modifiers are competitive on price and performance with the leading petroleum based core-shell impact modifiers, and offers the potential to reformulate the total additive package to achieve overall cost savings. These new biobased PHA modifiers allow PVC compounders and converters to create innovative new solutions and product offerings in a mature industry. In fact, Karen Laird of Plastics Today identified additives and modifiers as an area of bioplastics that will "strongly develop" in a recent article, "Bioplastics in 2013: 5 Trends to Watch."

At Metabolix, we've been exploring the versatility and range of our patented PHA backbone technology as we develop these impact modifiers for PVC. The development of biobased additives and modifiers represents a new part of the green tech story where materials valued for competitive performance also offer sustainability benefits. Metabolix is pleased to be taking part in this evolution and we look forward to bringing new biobased performance additives to market in 2013 and beyond.

Source: Metabolix

Purac to Commercialize PURALACT® Lactides to Produce PLA Homopolymers in Asian Biopolymer Mkt

Purac, a subsidiary of CSM, has signed a long term supply contract for the delivery of up to 10,000 tons annually of PURALACT® lactides to a customer in Asia. PURALACT® lactides will be polymerized into high heat polylactic acid (PLA), a bioplastic made from annually renewable resources.

Commercial production of the partner's production facility is expected to start in the second half of 2014, but material for sampling and testing will be available shortly. The supply agreement for high optical purity lactides will enable Purac's partner to produce a range of high performance PLA homopolymers.

The target market for the partner's PLA is Asia, with a focus on high heat PLA for durable and demanding applications, such as automotive and electronics parts.

Further to the supply agreement, Purac and its partner have signed a joint development agreement where Purac's know-how in the area of high performance PLA will be combined with the partner's market access and application knowledge to further accelerate the commercialization of PLA compounds for injection molding and extrusion purposes.

Source: Purac

Roquette Launches Sorbitol-based Clarifier DISORBENE® 3 for Polymer Industry

Roquette has a wide experience in producing sorbitol-based clarifiers using an efficient and environmentally sustainable production process. By offering DISORBENE® 3, Roquette opens a new reputable source for bis-DMBS, a state-of-the-art clarifier developed and sold by Millikenunder the registered trade name Millad® 3988, and provides additional capacity for this widely used clarifier to meet the growing needs of the polymer industry.

"Roquette has proven to be a very good partner to the polymer industry for the first and second generation sorbitol-based clarifiers in the past" points out Industry expert Dr. Felix Meyer, "and DISORBENE® 3 has the same quality standards and the advantageous granulometry of the Industry reference".

"Polypropylene producers in Europe are welcoming Roquette decision to re-enter the clarifier business as they were depending on one non-European supplier in the past" commented Mr. Thierry Laurent, head of Roquette Plant-based solutions department. "Roquette has recently created a new unit "Performance Plastics" to strengthen its link to the polymer industry".

Next to DISORBENE®, Roquette is offering the following plant-based solutions for the polymer industry:

• GAIALENE® — plant-based resins

• POLYSORB® (isosorbide)

• Reverdia Biosuccinium

• POLYSORB® ID — phthalate-free plasticizer.

Source: Roquette

Ticona at SAMPE: Highlighted Thermoplastic Solutions for Continuous-fiber Composites

Ticona, the engineering polymers business of Celanese Corporation, showcased its thermoplastics for composites at SAMPE 2013 [May 7 to 9], at the Long Beach Convention Center in California.

The Ticona exhibit highlighted thermoplastic solutions for continuous-fiber composites used in light and tough components that can reduce weight, drive down costs and perform in extreme environments.

The Ticona team also discussed the advantages of its thermoplastics and composites product line that includes:

– Fortron® polyphenylene sulfide (PPS) delivers proven production performance in critical aerospace structures, including the JEC 2013 Innovation Award-winning lightweight horizontal tailplane on the AgustaWestland AW169 helicopter.

• Superior FST (flame, smoke, toxicity) performance — exceeds aircraft interior requirements
• High-temperature performance to 240 degrees Celsius (as demonstrated under-the-hood)
• Superior dimensional stability (low shrink, CTE and creep)
• Broad chemical resistance to fuels, oils, solvents, fluids, strong acids, bases (pH 2-12), even at elevated temperatures
• Substantial cost savings vs. other high-temperature polymers

– Celstran® continuous fiber reinforced thermoplastics (CFR-TP) for unidirectional tapes, rods and profiles.

• Low weight with high stiffness and toughness
• Excellent impregnation technology
• High-performance dimensional, mechanical and thermal properties
• Superior chemical and corrosion resistance
• Wide range of resins, fibers and additives

Source: Celanese and Ticona

Arkema launches the Rilsan T, a new range of biosourced polyamides

Rilsan T represents an alternative to other long chain polyamides.

Arkema offers expertise spanning over 60 years in the chemistry of castor oil, the raw material for its Rilsan polyamide 11. This position was bolstered in 2012 by the acquisition of Chinese companies Casda, the world leader in sebacic acid derived from castor oil, and Hipro Polymers, which produces polyamides also from castor oil (Hiprolon PA6.10, PA6.12, PA10.10, PA10.12), as well as the recent purchase of a stake in Ihsedu Agrochem, a subsidiary of Jayant Agro in India which specializes in the production of castor oil. Building on its unique integration and an already unsurpassed offering in high performance polyamides, Arkema has now enhanced its product range with Rilsan PA.10.10 T processed from castor oil.

Arkema’s PA10.10 is ranked between PA6.10, PA6.12 on the one hand, and PA10.12, PA12, PA11 on the other, all of which are already part of Arkema’s product range. Over and above the well-known properties of long chain polyamides (chemical resistance, low moisture absorption, mechanical properties), Rilsan T affords an excellent degree of rigidity (in particular when reinforced with glassfiber), thermal stability, permeability to petrol and gas, and processability, while consisting of up to 100% renewable carbon.

 
Rilsan T also benefits from what sets Arkema’s polyamides apart in terms of technical possibilities (e.g. exclusive multilayer solutions for transport markets) and services (it qualifies for the exclusive RcycleTM offer of service which covers the collection, sorting and recycling of waste, and the development of a range of recycled polymers).

 
The various PA10.10 grades already available cover most applications in the field of transport (monolayer or multilayer brake lines for trucks and fuel lines for cars), industrial pipes, cables, and injection molded parts for sports or electronics applications.

Source:ARKEMA

UA-led Research Team Transforms Waste Sulfur into Plastic to Enrich Batteries for Electric Cars

A new chemical process can transform waste sulfur into a lightweight plastic that may improve batteries for electric cars, reports a University of Arizona-led team. The new plastic has other potential uses, including optical uses.

The team has successfully used the new plastic to make lithium-sulfur batteries.

"We've developed a new, simple and useful chemical process to convert sulfur into a useful plastic," lead researcher Jeffrey Pyun said.

Next-generation lithium-sulfur, or Li-S, batteries will be better for electric and hybrid cars and for military uses because they are more efficient, lighter and cheaper than those currently used, said Pyun, a UA associate professor of chemistry and biochemistry.

The new plastic has great promise as something that can be produced easily and inexpensively on an industrial scale, he said.

The team's discovery could provide a new use for the sulfur left over when oil and natural gas are refined into cleaner-burning fuels.

Although there are some industrial uses for sulfur, the amount generated from refining fossil fuels far outstrips the current need for the element. Some oil refineries, such as those in Ft. McMurray in Alberta, are accumulating yellow mountains of waste sulfur.

"There's so much of it we don't know what to do with it," said Pyun. He calls the left-over sulfur "the garbage of transportation."

About one-half pound of sulfur is left over for every 19 gallons of gasoline produced from fossil fuels, calculated co-author Jared Griebel, a UA chemistry and biochemistry doctoral candidate.

The researchers have filed an international patent for their new chemical process and for the new polymeric electrode materials for Li-S batteries.

The international team's research article, "The Use of Elemental Sulfur as an Alternative Feedstock for Polymeric Materials," was scheduled for online publication in Nature Chemistry on April 14. The National Research Foundation of Korea, the Korean Ministry of Education, Science and Technology, the American Chemical Society and the University of Arizona funded the research.

Pyun and Griebel's co-authors are Woo Jin Chung, Adam G. Simmonds, Hyun Jun Ji, Philip T. Dirlam, Richard S. Glass and Árpád Somogyi of the UA; Eui Tae Kim, Hyunsik Yoon, Jungjin Park, Yung-Eun Sung, and Kookheon Char of Seoul National University in Korea; Jeong Jae Wie, Ngoc A. Nguyen, Brett W. Guralnick and Michael E. Mackay of the University of Delaware in Newark; and Patrick Theato of the University of Hamburg in Germany.

Pyun wanted to apply his expertise as a chemist to energy-related research. He knew about the world's glut of elemental sulfur at fossil fuel refineries — so he focused on how chemistry could use the cheap sulfur to satisfy the need for good Li-S batteries.

He and his colleagues tried something new: transforming liquid sulfur into a useful plastic that eventually could be produced easily on an industrial scale.

Sulfur poses technical challenges. It doesn't easily form the stable long chains of molecules, known as polymers, needed make a moldable plastic, and most materials don't dissolve in sulfur.

Pyun and his colleagues identified the chemicals most likely to polymerize sulfur and girded themselves for the long process of testing those chemicals one by one by one. More than 20 chemicals were on the list.

They got lucky.

"The first one worked — and nothing else thereafter," Pyun said.

Even though the first experiment worked, the scientists needed to try the other chemicals on their list to see if others worked better and to understand more about working with liquid sulfur.

They've dubbed their process "inverse vulcanization" because it requires mostly sulfur with a small amount of an additive. Vulcanization is the chemical process that makes rubber more durable by adding a small amount of sulfur to rubber.

The new plastic performs better in batteries than elemental sulfur, Pyun said, because batteries with cathodes made of elemental sulfur can be used and recharged only a limited number of times before they fail.

The new plastic has electrochemical properties superior to those of the elemental sulfur now used in Li-S batteries, the researchers report. The team's batteries exhibited high specific capacity (823 mAh/g at 100 cycles) and enhanced capacity retention.

Several companies have expressed interest in the new plastic and the new battery, Pyun said.

The team's next step is comparing properties of the new plastic to existing plastics and exploring other practical applications such as photonics for the new plastic.

Source: University of Arizona