Saturday, September 14, 2024

Today's KNOWLEDGE Share :TOP PERFORMING HEAT RESISTANT PLASTICS

Today's KNOWLEDGE Share

TOP-PERFORMING HEAT RESISTANT PLASTICS

There are numerous types of heat resistant plastics available, each of which has unique advantages and disadvantages that make it suitable for different applications.



Some of the top-performing ones are:

PTFE (polytetrafluoroethylene). PTFE—commonly known by the brand name Teflon™—is characterized by its low coefficient of friction and high chemical resistance. It also demonstrates excellent flexural strength, electrical resistance, weather resistance, and thermal stability.It is suitable for use

in temperatures ranging from -328° F to 500° .


PEEK (polyetheretherketone). PEEK is a high-performance engineering thermoplastic with a semi-crystalline structure. It is resistant to chemicals, creep, fatigue, heat, and wear and has the highest flexural and tensile strength of any high-performance polymer. These qualities make it a suitable alternative to metals as they allow the material to remain strong and adaptable in harsh environmental conditions. It is suitable for continuous operating temperatures up to 500° .


PEI (polyetherimide). PEI—commonly only by the brand name Ultem®—is one of a handful of commercially available amorphous thermoplastics. It is strong, chemical resistant, and flame resistant and has the highest dielectric strength of any high-performance thermoplastic. It is suitable for continuous service temperatures up to 338°.


TYPICAL APPLICATIONS OF HEAT RESISTANT PLASTICS:

Heat resistant plastics are available in many forms, such as heat resistant plastic sheets. These various material forms are used to manufacture parts and products for a wide range of industries.


For example:

They are used for heat and shock resistant components in the aerospace, automotive, and glass industries.

They are used for heat resistant, emission proof, highly insulating, or defined conducting components in the electrical and semiconductor industries.

They are used for sterilization and hydrolysis proof components for the medical device industry.


They are used for emission proof and radiation resistant components for the nuclear energy and X-ray technology industries.

They are used for various components in the chemical industry.


source:newprocess.com

Thursday, September 12, 2024

Today's KNOWLEDGE Share : Fungal Mycelium as the Basis for Sustainable Products

Today's KNOWLEDGE Share

Fungi have more to offer than meets the eye. Their thread-like cells, which grow extensively and out of sight underground like a network of roots, offer huge potential for producing sustainable, biodegradable materials. Researchers at the Fraunhofer Institute for Applied Polymer Research IAP in Potsdam Science Park are using this mycelium to develop a wide range of recyclable products, from wallets and insulation to packaging.



Fungal Mycelium as the Basis for Sustainable Products:

To most of us, fungi look like a curved cap and a stem. However, the largest part of the organism consists of a network of cell filaments called mycelium, which mainly spreads below ground and can reach significant proportions. This finely branched network has been underutilized until now. However, for researchers at the Fraunhofer Institute for Applied Polymer Research IAP in Potsdam, mycelium represents a pioneering raw material with the potential to replace petroleum-based products with natural, organic mycelium composites. Organic residues from regional agricultural and forestry activities are used as the substrate for the fungal cultures. In various projects, the researchers are using mycelium-based materials to produce insulation, packaging, and animal-free alternatives to leather products.


Mycelium-based materials from regional agricultural residues:

“Faced with climate change and dwindling fossil raw materials, there is an urgent need for biodegradable materials that can be produced with lower energy consumption,” says Dr. Hannes Hinneburg, a biotechnologist at Fraunhofer IAP. Together with his team, he is using mycelium — for instance, from edible mushrooms or bracket fungi such as the oyster mushroom or tinder fungus — to transform locally available plant residues into sustainable materials. “The mycelium has properties that can be used to produce environmentally friendly, energy-efficient materials, since the growth of the fungi takes place under ambient conditions and CO2 remains stored in the residues. When cellulose and other organic residues decompose, a compact, three-dimensional network forms, enabling a self-sustaining structure to develop,” explains Hinneburg. This produces a material that is a complex compound with an organic substrate such as cereal residues, wood chips, hemp, reeds, rape or other agricultural residues. These substances are a source of nutrients for the fungus and are permeated entirely by a fine network of mycelia during the metabolic process. This produces a fully organic composite that can be made into the required shape and stabilized through thermal treatment. “First, you mix water together with agricultural residues such as straw, wood chips and sawdust to form a mass. Once the level of humidity and particle size have been determined, and the subsequent heat treatment to kill off competing germs has been completed, the substrate is ready. It provides food for the fungi and is mixed with the mycelium. Following a growth phase of around two to three weeks in the incubator, the mixture will produce, depending on the formulation and process used, a substance similar to leather or a composite that can be processed further,” says Hinneburg, summarizing the production process. No light is required for this process — a bonus as far as energy efficiency is concerned.


Versatile applications: 

strength and elasticity can be specifically configured The fungal materials can be cultivated with a wide range of properties. Depending on the application, they can be hard-wearing, stretchable, tear-resistant, impermeable, elastic, soft and fluffy, or open-pored. The result is determined by the combination of the type of fungus and agricultural residues, plus variable parameters such as temperature and humidity. The duration of mycelial growth also influences the end product. The versatility of the material means it can take on a huge variety of forms, from thick blocks to wafer-thin layers, and be used in a multitude of scenarios. This makes it possible to use fungi-based materials for textile upholstery, packaging, furniture, bags or insulation boards for interiors. When used as a construction material, the fungus primarily functions as a biological adhesive since a wide range of organic particles are joined together via the mycelium.

“The many positive properties of the material, heat-insulating, electrically insulating, moisture-regulating and fire-resistant, enable an important step toward circular and climate-positive construction,” says Hinneburg, one of whose current projects involves developing a novel polystyrene alternative for thermal insulation. In another project, he is working alongside the Institute for Food and Environmental Research and Agro Saarmund e.G. to produce environmentally friendly, mycelium-based packaging trays from residues and raw materials sourced from local agricultural and forestry activities. In work he has done with designers, he has also developed the base material for animal-free alternatives to leather products such as bags and wallets. As the mycelium-based materials look similar to their leather counterparts, they can be used to complement leather items in certain areas.

Developing industrial processes

In Europe, only a few companies are currently developing mycelium-based materials for commercial use. The challenges in this area include access to biogenic residues, the ability to ensure consistent product quality and the means to scale up activities efficiently.

To address these challenges, the researchers are using a newly developed roll-to-roll method, for which they have already created a prototype. This method offers significant advantages over standard manufacturing processes involving boxes and shelving systems: By using a standardized, continuous production method under controlled process conditions (such as temperature and humidity), the researchers can ensure that the mycelium-based products have consistent material properties. What’s more, resources can be used more efficiently, and production can be scaled to an industrial level. “This is crucial in order to meet growing industry demand for sustainable materials and to become less dependent on petroleum in the long term. Production can also be improved further by using innovative technologies such as artificial intelligence to optimize the combination of residues and types of fungi,” says Hinneburg.


Source: Fraunhofer-Gesellschaft



Wednesday, September 11, 2024

RESICARE ANNOUNCES AVAILABILITY OF THE FIRST SAMPLES OF THE NON-TOXIC, BIO-BASED MOLECULE 5-HMF FOR INDUSTRIAL USE

ResiCare, a subsidiary of the Michelin Group, and IFPEN announced last November the development of a bio-based production process for the platform molecule 5-HMF(5-hydroxymethylfurfural). Non-toxic* and produced from plant-based fructose, this molecule offers industries a substitute for fossil-based products. The samples of the 5-HMF molecule produced by ResiCare are now available for industrial testing.

5-HMF is a particularly attractive platform molecule for the chemical industry, as it allows the replacement of fossil-based products with bio-based alternatives in numerous application areas: adhesives and resins, plastic polymers, solvents and acids, amines and amides, fuels and fuel additives, pharmaceuticals, and human and animal nutrition.


ResiCare, a subsidiary of the Michelin Group, develops and markets innovative adhesive resins that combine high performance, non-toxicity, and renewable materials. Initially developed for the tire industry, ResiCare technology is now expanding into a range of industrial applications (wood, insulation, abrasives, composites, etc.).


source:ResiCare

Today's KNOWLEDGE Share :India's Greener future with Electric Mobility

Today's KNOWLEDGE Share

"India’s 10,900 Crore PM E-DRIVE: Powering a Greener Future with Electric Mobility!"



India is accelerating towards a greener future with the PM E-DRIVE Scheme, approved with a 10,900 crore outlay to revolutionize electric mobility. This initiative focuses on:


1. Subsidies/Demand Incentives : ₹3,679 crore allocated to encourage adoption of e-2Ws, e-3Ws, e-ambulances, e-trucks, and more, reducing emissions and costs.


2. E-Vouchers: Aadhaar-authenticated e-vouchers streamline the EV buying process, enhancing transparency and ease of access.


3. Electric Ambulances : ₹500 crore for e-ambulances to lower healthcare's carbon footprint and innovate public service.


4. Incentives for Scrapping Old Trucks: Encourages replacing polluting trucks with e-trucks, promoting a sustainable logistics sector.


5. Vehicle Testing Infrastructure*: ₹780 crore dedicated to enhancing testing standards for safety and performance in EVs.


6. Procurement of E-Buses: ₹4,391 crore for 14,028 e-buses, improving public transport and reducing urban emissions.


The PM E-DRIVE Scheme not only supports economic growth and job creation but also commits to environmental sustainability and technological advancement. This landmark initiative positions India as a leader in the electric mobility revolution, significantly contributing to global climate goals. Together, we can build a cleaner, healthier future.


source:Dr.Venugopal R, JtCCOE-PESO

Avient Introduces PFAS-free Fiber Solution for Ballistic and Personal Protection

Dyneema®, owned by Avient Corporation, to provide ultra-high-molecular-weight polyethylene (UHMWPE) fiber, unidirectional (UD) composite fabric, and film materials that are manufactured without intentionally added per- and polyfluoroalkyl substances (PFAS) for hard and soft ballistic armor, helmets, and vehicle armor.


Also, unlike para-aramid alternatives, the unique properties of Dyneema®, enable personal protection products that can achieve desirable levels of water, liquid, and oil-repellency without a need for PFAS-based surface treatments.


Addressing Supply Chain Uncertainty of PFAS Materials:

Certain PFAS are often used in a range of personal protection products, including in their manufacturing processes or surface treatments. However, a growing body of research suggests that many PFAS break down very slowly over time and can persist in water and soil in the environment. As a result, authorities in the United States and beyond are considering actions to limit PFAS.


At the North Carolina FEDTEX 2024 Conference, the US Army Combat Capabilities Development Command (DEVCOM) Soldier Center warned that solutions containing PFAS are becoming less readily available because of regulatory and supply chain uncertainty. According to the DEVCOM Soldier Center, there is an urgent need to move toward non-PFAS alternatives within the personal protection industry.


One material currently used to make personal protective products is para-aramid. However, para-aramid-based solutions require a surface treatment, which typically is PFAS-based, to repel liquids, such as water and oils, because moisture and oil can negatively affect the ballistic performance of para-aramid fibers. In contrast, the unique properties of Dyneema® materials make them inherently resistant to moisture and easy to wipe clean – meaning there is no need to apply a PFAS-containing surface treatment.


Offering Ultra-low Weight with Maximum Stopping Power:

Thanks to its unique manufacturing process and performance properties, the Dyneema® brand signifies that its fiber, UD material, and film are made without intentionally added PFAS. For the American market, Dyneema® fiber – with its unrivaled strength-to-weight ratio – is manufactured in Greenville, North Carolina. The Greenville site employs more than 400 American workers, 10% of whom are military veterans. The facility is also close to the Dyneema® business’s US Technical Service Center, where its ballistic experts support armor manufacturers in developing next-generation products capable of standing up to legacy and emerging threats.


Source: Avient Corporation/www.polymer-additives.specialchem.com

Today's KNOWLEDGE Share :Thermochromic Polymer Blend Enables Energy-efficient Indoor Space Cooling

Today's KNOWLEDGE Share

New Smart Thermochromic Polymer Blend Enables Energy-efficient Indoor Space Cooling

Rice University researchers have developed a smart material that adjusts its transparency with changes in temperature, outperforming similar materials in terms of durability, transparency and responsiveness.


The new polymer blend could significantly enhance energy efficiency for indoor space cooling, according to a new study published in Joule.


Becomes Less Transparent as the Day Gets Warmer


Cooling off can be a matter of life or death, but air conditioning ⎯ when and if available ⎯ already accounts for 7% of the world’s energy use and 3% of carbon emissions. With temperatures hitting record highs and heat waves growing more frequent worldwide, the need for more efficient ways to keep indoor temperatures in check has also grown more urgent.


One way to mitigate the issue involves coating windows with materials that keep heat out while still allowing light to pass through. One such class of materials is thermochromics, yet existing varieties are still too expensive and short-lived to make a feasible choice for use in buildings, vehicles and wherever else needed.


The new salted polymer blend system developed by Rice engineers in the Nanomaterials Laboratory led by Pulickel Ajayan overcomes these challenges, potentially enabling the large-scale deployment of thermochromics as an energy-efficient indoor space cooling technology.


“Imagine a window that becomes less transparent as the day gets warmer, keeping interiors cool without consuming energy,” said Sreehari Saju, a materials science and nanoengineering doctoral student at Rice who is a co-lead author on the study. “Our formulation leverages both organic and inorganic components to overcome the limitations of existing thermochromic materials such as short lifespans and high costs.


“Moreover, this material’s thermic response is well-matched to real-world environmental demands. We think that smart windows made from this material could significantly reduce energy consumption in buildings, making a tangible impact on both energy costs and carbon footprint.”


Mixed Two Polymers with a Salt


The researchers combined experimental methods with computational simulations to understand the material’s behavior under different environmental and architectural settings. For instance, they assessed how the material would perform in specific urban areas around the world to get a sense of its potential impact when deployed at scale.


The researchers synthesized the material by mixing two polymers with a type of salt and worked on optimizing the composition to achieve smooth transitions between transparent and opaque states with temperature fluctuations. Their findings show that the new thermochromic blend is not only highly effective in regulating solar radiation but also remarkably durable with an estimated lifespan of 60 years.


Source: Rice University/www.omnexus.specialchem.com

Sunday, September 8, 2024

Today's KNOWLEDGE Share :Frozen Layer thickness

Today's KNOWLEDGE Share

When trying to model Injection Molding one has to determine the transient frozen layer thickness.


And it is more tricky than most might think.


For amorphous polymers the best transition temperature would be available straight from the PvT data and will even include the important pressure dependence. It will however not include any cooling rate dependence and Tg is extremely sensitive to cooling rate, as people observe daily with DSC

PvT is essentially measured in a quiescent state close to thermodynamic equilibrium (very slow heat/cool rates).


For semi-crystalline materials the problem is worse. We need to capture the crystallization temperature which is pressure dependent also (that can be seen in PvT) but extremely dependent on cooling rate (crystallization kinetics aspects).

Furthermore, the strong nucleation effect of shear-stress close to the outer layers will dramatically increase, locally, this transition temperature. Which means the transition temperature will be very different from skin to core.


In essence, there is not such a thing as ONE no flow temperature or transition temperature.

To preserve mass balance in molding simulation it will also be of key importance to perfectly "sync" the phase change for all physical properties (PvT, thermal data, viscosity,...).


We still have a long way to go to fully capture this complex physics in our beloved commercial software tools.

The best attempt I know of, was an old Research Release version of Moldflow, work I was involved in) including explicit crystallization kinetics and implementing "dynamic" PvT (transition zone driven by real kinetics), with full sync of all other variables.


source:Vito leo

WORKPLACE FLOOR MARKINGS : Simple Lines. Clear Rules. Fewer Incidents.

  WORKPLACE FLOOR MARKINGS Simple Lines. Clear Rules. Fewer Incidents. Clear floor markings are a visual management tool that improves safet...